TY - JOUR
T1 - Pore characteristics of carbide-derived carbons obtained from carbides with different carbon volume fractions
AU - Xu, Jiang
AU - Wu, Chao
AU - Yan, Pengtao
AU - Zhang, Ruijun
AU - Yue, Xueqing
AU - Ge, Shanhai
N1 - Funding Information:
This work was supported by the National Natural Science Foundation of China (No. 50975247 ), the Project of Science and Technology Plan of Hebei Province (No. 12211102 ).
PY - 2014/11/1
Y1 - 2014/11/1
N2 - Porous carbide-derived carbons (CDCs) are synthesized by chlorination of carbides with different carbon volume fractions in the temperature range from 400 to 1000 °C. It is found that the volume fraction of carbon atoms in carbide precursor has much influence on pore structure of the produced CDC. It is prone to form well ordered graphite to chlorinate carbides with high carbon volume fraction (e.g. VC and TiC). Interlayer spacing of the produced graphite is about 0.34 nm. Its thickness increases with chlorination temperature, which leads to a monotonous increase of pore size in the produced CDC. As for the CDCs synthesized from carbides with low carbon volume fraction (e.g. NbC), it is mainly composed of single or bi-layer graphene. The pore size distribution of these NbC-CDCs is insensitive to chlorination temperature. NbC-CDC synthesized at moderate temperature (600 or 800 °C) contains a large amount of micropores (∼0.8 nm) and small amount of mesopores. Since almost all of these micropores are end-opened, the produced NbC-CDC has high specific surface area (>2000 m2 g-1).
AB - Porous carbide-derived carbons (CDCs) are synthesized by chlorination of carbides with different carbon volume fractions in the temperature range from 400 to 1000 °C. It is found that the volume fraction of carbon atoms in carbide precursor has much influence on pore structure of the produced CDC. It is prone to form well ordered graphite to chlorinate carbides with high carbon volume fraction (e.g. VC and TiC). Interlayer spacing of the produced graphite is about 0.34 nm. Its thickness increases with chlorination temperature, which leads to a monotonous increase of pore size in the produced CDC. As for the CDCs synthesized from carbides with low carbon volume fraction (e.g. NbC), it is mainly composed of single or bi-layer graphene. The pore size distribution of these NbC-CDCs is insensitive to chlorination temperature. NbC-CDC synthesized at moderate temperature (600 or 800 °C) contains a large amount of micropores (∼0.8 nm) and small amount of mesopores. Since almost all of these micropores are end-opened, the produced NbC-CDC has high specific surface area (>2000 m2 g-1).
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U2 - 10.1016/j.micromeso.2014.07.019
DO - 10.1016/j.micromeso.2014.07.019
M3 - Article
AN - SCOPUS:84905368916
VL - 198
SP - 74
EP - 81
JO - Microporous and Mesoporous Materials
JF - Microporous and Mesoporous Materials
SN - 1387-1811
ER -