TY - JOUR
T1 - Post-application of dry vortex grinding improves the yield of a [2 + 2] photodimerization
T2 - Addressing static disorder in a cocrystal
AU - Elacqua, Elizabeth
AU - Kummer, Katherine A.
AU - Groeneman, Ryan H.
AU - Reinheimer, Eric W.
AU - MacGillivray, Leonard R.
N1 - Funding Information:
We are grateful to Webster University for a Faculty Research Grant and Faculty Development Fund (R.H.G) as well as the National Science Foundation (L.R.M., DMR-1408834 ) for funding. The authors would also like to acknowledge California State University San Marcos for the funds to purchase the Rigaku SCXMini X-ray diffractometer.
Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2016/12/1
Y1 - 2016/12/1
N2 - A post-application of dry vortex grinding is used to improve a solid-state photodimerization to near quantitative yield that without grinding does not go to completion. Variable temperature X-ray crystal structure data support the vortex grinding to overcome detrimental effects of static disorder that suppresses the yield of the photoreaction in the solid.
AB - A post-application of dry vortex grinding is used to improve a solid-state photodimerization to near quantitative yield that without grinding does not go to completion. Variable temperature X-ray crystal structure data support the vortex grinding to overcome detrimental effects of static disorder that suppresses the yield of the photoreaction in the solid.
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U2 - 10.1016/j.jphotochem.2015.12.004
DO - 10.1016/j.jphotochem.2015.12.004
M3 - Article
AN - SCOPUS:84955615666
SN - 1010-6030
VL - 331
SP - 42
EP - 47
JO - Journal of Photochemistry and Photobiology A: Chemistry
JF - Journal of Photochemistry and Photobiology A: Chemistry
ER -