Potassium niobate nanoscrolls incorporating rhodium hydroxide nanoparticles for photocatalytic hydrogen evolution

Renzhi Ma, Yoji Kobayashi, W. Justin Youngblood, Thomas E. Mallouk

Research output: Contribution to journalArticle

41 Scopus citations

Abstract

Well-dispersed rhodium trihydroxide nanoparticles (below 1 nm) were deposited into the interlayer galleries of scrolled K4Nb 6O17 nanosheets. The unmodified nanoscrolls are good catalysts for UV light-driven hydrogen evolution from aqueous methanol solutions, and their activity can be significantly improved by anchoring a small amount (0.1 wt% Rh) of Rh(OH)3 or Rh2O3 to the surface. The high hydrogen generation rate achieved in this system, 1480 mol/h per 1g of catalyst, shows promise towards overall water splitting using these catalytic composites.

Original languageEnglish (US)
Pages (from-to)5982-5985
Number of pages4
JournalJournal of Materials Chemistry
Volume18
Issue number48
DOIs
StatePublished - Dec 15 2008

    Fingerprint

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Chemistry

Cite this