Preparation and X-ray structures of 2-[(aryl)iodonio]benzenesulfonates: novel diaryliodonium betaines

Michael Walter Justik; John D. Protasiewicz; James B. Updegraff

doi:10.1016/j.tetlet.2009.08.067

Preparation and X-ray structures of 2-[(aryl)iodonio]benzenesulfonates: novel diaryliodonium betaines

Michael Walter Justik, John D. Protasiewicz, James B. Updegraff

School of Science (Behrend)

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Herein we present a concise preparation and characterization of 2-[(aryl)iodonio]benzenesulfonates. Determination of the X-ray crystal structure reveals a distorted trigonal bipyramidal molecular geometry about iodine and a pseudo-square geometry within the unit cell. Initial experiments point to the promising application of these compounds for unique 2-sulfonyloxyarenes.

Original language	English (US)
Pages (from-to)	6072-6075
Number of pages	4
Journal	Tetrahedron Letters
Volume	50
Issue number	44
DOIs	https://doi.org/10.1016/j.tetlet.2009.08.067
State	Published - Nov 4 2009

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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abstract = "Herein we present a concise preparation and characterization of 2-[(aryl)iodonio]benzenesulfonates. Determination of the X-ray crystal structure reveals a distorted trigonal bipyramidal molecular geometry about iodine and a pseudo-square geometry within the unit cell. Initial experiments point to the promising application of these compounds for unique 2-sulfonyloxyarenes.",

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AU - Updegraff, James B.

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AB - Herein we present a concise preparation and characterization of 2-[(aryl)iodonio]benzenesulfonates. Determination of the X-ray crystal structure reveals a distorted trigonal bipyramidal molecular geometry about iodine and a pseudo-square geometry within the unit cell. Initial experiments point to the promising application of these compounds for unique 2-sulfonyloxyarenes.

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