Preparation and X-ray structures of 2-[(aryl)iodonio]benzenesulfonates: novel diaryliodonium betaines

Michael Walter Justik, John D. Protasiewicz, James B. Updegraff

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

Herein we present a concise preparation and characterization of 2-[(aryl)iodonio]benzenesulfonates. Determination of the X-ray crystal structure reveals a distorted trigonal bipyramidal molecular geometry about iodine and a pseudo-square geometry within the unit cell. Initial experiments point to the promising application of these compounds for unique 2-sulfonyloxyarenes.

Original languageEnglish (US)
Pages (from-to)6072-6075
Number of pages4
JournalTetrahedron Letters
Volume50
Issue number44
DOIs
StatePublished - Nov 4 2009

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Fingerprint Dive into the research topics of 'Preparation and X-ray structures of 2-[(aryl)iodonio]benzenesulfonates: novel diaryliodonium betaines'. Together they form a unique fingerprint.

Cite this