Preparation of the elusive [(por)Fe(NO)(O-ligand)] complex by diffusion of nitric oxide into a crystal of the precursor

Nan Xu, Lauren E. Goodrich, Nicolai Lehnert, Douglas R. Powell, George B. Richter-Addo

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

A crystal-gas method was used to prepare neutral [(por)Fe(NO)(O-ligand)] complexes. [(por)Fe(NO)(OC(=O)CF3)] has an almost linear Fe-NO moiety. Porphyrin molecules move dramatically in the crystal upon NO diffusion into the lattice and binding to Fe. DFT calculations on this and related complexes provide insight into the trans effects of axial ligands on the Fe-NO angle.

Original languageEnglish (US)
Pages (from-to)3896-3900
Number of pages5
JournalAngewandte Chemie - International Edition
Volume52
Issue number14
DOIs
StatePublished - Apr 2 2013

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Nitric oxide
Nitric Oxide
Ligands
Crystals
Porphyrins
Discrete Fourier transforms
Crystal lattices
Gases
Molecules

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Xu, Nan ; Goodrich, Lauren E. ; Lehnert, Nicolai ; Powell, Douglas R. ; Richter-Addo, George B. / Preparation of the elusive [(por)Fe(NO)(O-ligand)] complex by diffusion of nitric oxide into a crystal of the precursor. In: Angewandte Chemie - International Edition. 2013 ; Vol. 52, No. 14. pp. 3896-3900.
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Preparation of the elusive [(por)Fe(NO)(O-ligand)] complex by diffusion of nitric oxide into a crystal of the precursor. / Xu, Nan; Goodrich, Lauren E.; Lehnert, Nicolai; Powell, Douglas R.; Richter-Addo, George B.

In: Angewandte Chemie - International Edition, Vol. 52, No. 14, 02.04.2013, p. 3896-3900.

Research output: Contribution to journalArticle

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