Products, Pathways, and Kinetics for the Fast Hydrothermal Liquefaction of Soy Protein Isolate

James D. Sheehan, Phillip E. Savage

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

We conducted nonisothermal fast hydrothermal liquefaction (HTL) of soy protein isolate (SPI) for batch holding times of 10-300 s and at temperatures up to 500 °C. The SPI solids rapidly formed water-soluble products, some of which subsequently formed biocrude. The highest biocrude yields (38-40 wt %) were obtained within 45-120 s, at which times the reactor temperatures had reached 375-435 °C. The highest recovery of nitrogen in the aqueous-phase products (80% of that present in SPI) occurred prior to formation of high biocrude yields. Ammonia formation was significant when the hydrothermal reaction medium reached supercritical conditions; over 50% of the atomic N appeared as ammonia under such conditions. We deduced the reaction pathways and developed a kinetic model from the experimental data. The reaction network includes two types of aqueous-phase products formed during HTL of protein. The first type arises directly from the SPI and the second arise from biocrude. The model accurately correlated the product yields under the fast HTL experimental conditions studied, and it accurately predicted the yields of product fractions from isothermal HTL of SPI at 300 and 350 °C.

Original languageEnglish (US)
Pages (from-to)6931-6939
Number of pages9
JournalACS Sustainable Chemistry and Engineering
Volume4
Issue number12
DOIs
StatePublished - Dec 5 2016

Fingerprint

Soybean Proteins
Liquefaction
liquefaction
Proteins
kinetics
Kinetics
protein
Ammonia
ammonia
Nitrogen
product
Recovery
temperature
Temperature
Water
nitrogen

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Environmental Chemistry
  • Chemical Engineering(all)
  • Renewable Energy, Sustainability and the Environment

Cite this

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abstract = "We conducted nonisothermal fast hydrothermal liquefaction (HTL) of soy protein isolate (SPI) for batch holding times of 10-300 s and at temperatures up to 500 °C. The SPI solids rapidly formed water-soluble products, some of which subsequently formed biocrude. The highest biocrude yields (38-40 wt {\%}) were obtained within 45-120 s, at which times the reactor temperatures had reached 375-435 °C. The highest recovery of nitrogen in the aqueous-phase products (80{\%} of that present in SPI) occurred prior to formation of high biocrude yields. Ammonia formation was significant when the hydrothermal reaction medium reached supercritical conditions; over 50{\%} of the atomic N appeared as ammonia under such conditions. We deduced the reaction pathways and developed a kinetic model from the experimental data. The reaction network includes two types of aqueous-phase products formed during HTL of protein. The first type arises directly from the SPI and the second arise from biocrude. The model accurately correlated the product yields under the fast HTL experimental conditions studied, and it accurately predicted the yields of product fractions from isothermal HTL of SPI at 300 and 350 °C.",
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Products, Pathways, and Kinetics for the Fast Hydrothermal Liquefaction of Soy Protein Isolate. / Sheehan, James D.; Savage, Phillip E.

In: ACS Sustainable Chemistry and Engineering, Vol. 4, No. 12, 05.12.2016, p. 6931-6939.

Research output: Contribution to journalArticle

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