Radiation crosslinking of poly[bis-2-(2-methoxyethoxy)ethoxy]phosphazene: effect on solid state ionic conductivity

Jordan L. Bennett, Alexa A. Dembek, Harry R. Allcock, Bruce J. Heyen, Duward F. Shriver

Research output: Contribution to journalConference article

8 Citations (Scopus)

Abstract

The polyphosphazene, poly[bis(2-2-methoxyethoxy) ethoxy]phosphazene (I), shows excellent promise as a solid electrolyte host when LiCF3SO3 is used as the charge carrier. The ionic conductivity of the gamma irradiated crosslinked polymer/salt complexes was investigated through two complementary sets of polymer-electrolyte combinations. In one (series A) the salt was added to the polymer before irradiation, while in the second (series B) the salt was added to a solvent-swelled polymer after irradiation. These experiments were carried out to eliminate the possibility that the presence of LiCF3SO3 during irradiation would affect the ionic conductivity of the final product. Series A and B each consisted of six thin films of I with 0.25 equivalent of LiCF3SO3 per polymer repeat unit.

Original languageEnglish (US)
Pages (from-to)437-438
Number of pages2
JournalAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
Volume30
Issue number1
StatePublished - Apr 1 1989
EventPapers Presented at the Dallas, Texas Meeting - Dallas, TX, USA
Duration: Apr 9 1989Apr 14 1989

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Ionic conductivity
Crosslinking
Polymers
Radiation
Salts
Irradiation
Solid electrolytes
Charge carriers
Electrolytes
Thin films
Experiments

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics

Cite this

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abstract = "The polyphosphazene, poly[bis(2-2-methoxyethoxy) ethoxy]phosphazene (I), shows excellent promise as a solid electrolyte host when LiCF3SO3 is used as the charge carrier. The ionic conductivity of the gamma irradiated crosslinked polymer/salt complexes was investigated through two complementary sets of polymer-electrolyte combinations. In one (series A) the salt was added to the polymer before irradiation, while in the second (series B) the salt was added to a solvent-swelled polymer after irradiation. These experiments were carried out to eliminate the possibility that the presence of LiCF3SO3 during irradiation would affect the ionic conductivity of the final product. Series A and B each consisted of six thin films of I with 0.25 equivalent of LiCF3SO3 per polymer repeat unit.",
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Radiation crosslinking of poly[bis-2-(2-methoxyethoxy)ethoxy]phosphazene : effect on solid state ionic conductivity. / Bennett, Jordan L.; Dembek, Alexa A.; Allcock, Harry R.; Heyen, Bruce J.; Shriver, Duward F.

In: American Chemical Society, Polymer Preprints, Division of Polymer Chemistry, Vol. 30, No. 1, 01.04.1989, p. 437-438.

Research output: Contribution to journalConference article

TY - JOUR

T1 - Radiation crosslinking of poly[bis-2-(2-methoxyethoxy)ethoxy]phosphazene

T2 - effect on solid state ionic conductivity

AU - Bennett, Jordan L.

AU - Dembek, Alexa A.

AU - Allcock, Harry R.

AU - Heyen, Bruce J.

AU - Shriver, Duward F.

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Y1 - 1989/4/1

N2 - The polyphosphazene, poly[bis(2-2-methoxyethoxy) ethoxy]phosphazene (I), shows excellent promise as a solid electrolyte host when LiCF3SO3 is used as the charge carrier. The ionic conductivity of the gamma irradiated crosslinked polymer/salt complexes was investigated through two complementary sets of polymer-electrolyte combinations. In one (series A) the salt was added to the polymer before irradiation, while in the second (series B) the salt was added to a solvent-swelled polymer after irradiation. These experiments were carried out to eliminate the possibility that the presence of LiCF3SO3 during irradiation would affect the ionic conductivity of the final product. Series A and B each consisted of six thin films of I with 0.25 equivalent of LiCF3SO3 per polymer repeat unit.

AB - The polyphosphazene, poly[bis(2-2-methoxyethoxy) ethoxy]phosphazene (I), shows excellent promise as a solid electrolyte host when LiCF3SO3 is used as the charge carrier. The ionic conductivity of the gamma irradiated crosslinked polymer/salt complexes was investigated through two complementary sets of polymer-electrolyte combinations. In one (series A) the salt was added to the polymer before irradiation, while in the second (series B) the salt was added to a solvent-swelled polymer after irradiation. These experiments were carried out to eliminate the possibility that the presence of LiCF3SO3 during irradiation would affect the ionic conductivity of the final product. Series A and B each consisted of six thin films of I with 0.25 equivalent of LiCF3SO3 per polymer repeat unit.

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