Rational design of gas chromatographic capillary column stationary phases

Franklin Lewis Dorman, Jr., Christopher M. English, Michael J. Feeney, Julie Kowalski

Research output: Contribution to specialist publicationArticle

Abstract

The development of the Rtx-CL Pesticides and Rtx-CL Pesticides2 columns demonstrates how computer modeling can be effectively employed in the design of stationary phases that yield optimum resolution for a specific list of compounds. In addition, these columns can be baked out the end of each analysis to remove high-boiling contaminants without degrading the stationary phase. They do not have the problems associated with cyanopropyl phases such as on-column methoxychlor and DDT breakdown and low maximum temperature. These application specific stationary phases will improve analyses that were previously difficult because of the reuse of general-purpose phases.

Original languageEnglish (US)
Volume31
No6
Specialist publicationAmerican Laboratory
StatePublished - Mar 1 1999

Fingerprint

Methoxychlor
DDT
Pesticides
Boiling liquids
Gases
Impurities
Temperature

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

Dorman, Jr., F. L., English, C. M., Feeney, M. J., & Kowalski, J. (1999). Rational design of gas chromatographic capillary column stationary phases. American Laboratory, 31(6).
Dorman, Jr., Franklin Lewis ; English, Christopher M. ; Feeney, Michael J. ; Kowalski, Julie. / Rational design of gas chromatographic capillary column stationary phases. In: American Laboratory. 1999 ; Vol. 31, No. 6.
@misc{34ab47c559e94e2cb7311a3034e07a26,
title = "Rational design of gas chromatographic capillary column stationary phases",
abstract = "The development of the Rtx-CL Pesticides and Rtx-CL Pesticides2 columns demonstrates how computer modeling can be effectively employed in the design of stationary phases that yield optimum resolution for a specific list of compounds. In addition, these columns can be baked out the end of each analysis to remove high-boiling contaminants without degrading the stationary phase. They do not have the problems associated with cyanopropyl phases such as on-column methoxychlor and DDT breakdown and low maximum temperature. These application specific stationary phases will improve analyses that were previously difficult because of the reuse of general-purpose phases.",
author = "{Dorman, Jr.}, {Franklin Lewis} and English, {Christopher M.} and Feeney, {Michael J.} and Julie Kowalski",
year = "1999",
month = "3",
day = "1",
language = "English (US)",
volume = "31",
journal = "American Laboratory",
issn = "0044-7749",
publisher = "International Scientific Communications Inc.",

}

Dorman, Jr., FL, English, CM, Feeney, MJ & Kowalski, J 1999, 'Rational design of gas chromatographic capillary column stationary phases' American Laboratory, vol. 31, no. 6.

Rational design of gas chromatographic capillary column stationary phases. / Dorman, Jr., Franklin Lewis; English, Christopher M.; Feeney, Michael J.; Kowalski, Julie.

In: American Laboratory, Vol. 31, No. 6, 01.03.1999.

Research output: Contribution to specialist publicationArticle

TY - GEN

T1 - Rational design of gas chromatographic capillary column stationary phases

AU - Dorman, Jr., Franklin Lewis

AU - English, Christopher M.

AU - Feeney, Michael J.

AU - Kowalski, Julie

PY - 1999/3/1

Y1 - 1999/3/1

N2 - The development of the Rtx-CL Pesticides and Rtx-CL Pesticides2 columns demonstrates how computer modeling can be effectively employed in the design of stationary phases that yield optimum resolution for a specific list of compounds. In addition, these columns can be baked out the end of each analysis to remove high-boiling contaminants without degrading the stationary phase. They do not have the problems associated with cyanopropyl phases such as on-column methoxychlor and DDT breakdown and low maximum temperature. These application specific stationary phases will improve analyses that were previously difficult because of the reuse of general-purpose phases.

AB - The development of the Rtx-CL Pesticides and Rtx-CL Pesticides2 columns demonstrates how computer modeling can be effectively employed in the design of stationary phases that yield optimum resolution for a specific list of compounds. In addition, these columns can be baked out the end of each analysis to remove high-boiling contaminants without degrading the stationary phase. They do not have the problems associated with cyanopropyl phases such as on-column methoxychlor and DDT breakdown and low maximum temperature. These application specific stationary phases will improve analyses that were previously difficult because of the reuse of general-purpose phases.

UR - http://www.scopus.com/inward/record.url?scp=0345103364&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0345103364&partnerID=8YFLogxK

M3 - Article

VL - 31

JO - American Laboratory

JF - American Laboratory

SN - 0044-7749

ER -

Dorman, Jr. FL, English CM, Feeney MJ, Kowalski J. Rational design of gas chromatographic capillary column stationary phases. American Laboratory. 1999 Mar 1;31(6).