Rational design of gas chromatographic capillary column stationary phases

Franklin Lewis Dorman, Jr., Christopher M. English, Michael J. Feeney, Julie Kowalski

Research output: Contribution to specialist publicationArticle

Abstract

The development of the Rtx-CL Pesticides and Rtx-CL Pesticides2 columns demonstrates how computer modeling can be effectively employed in the design of stationary phases that yield optimum resolution for a specific list of compounds. In addition, these columns can be baked out the end of each analysis to remove high-boiling contaminants without degrading the stationary phase. They do not have the problems associated with cyanopropyl phases such as on-column methoxychlor and DDT breakdown and low maximum temperature. These application specific stationary phases will improve analyses that were previously difficult because of the reuse of general-purpose phases.

Original languageEnglish (US)
Volume31
No6
Specialist publicationAmerican Laboratory
StatePublished - Mar 1 1999

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Biochemistry, Genetics and Molecular Biology(all)

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