Reaction of palladium 1,5-cyclooctadiene alkyl chloride with norbornene derivatives: Relevance to metal-catalyzed addition polymerization of functionalized norbornenes

Myeongsoon Kang, Ayusman Sen

Research output: Contribution to journalArticle

35 Citations (Scopus)

Abstract

The insertions of norbornene, bicyclo[2.2.1]-hept-5-ene-endo-2-carboxylic acid ethyl ester, bicyclo-[2.2.1]hept-5-ene-exo-2-carboxylic acid ethyl ester, and bicyclo[2.2.1]hept-5-enyl-endo-2-methyl acetate into the palladium-methyl bond of(η 4-cycloocta-1,5-diene)chloromethylpalladium(II) were found to proceed at similar rates, with the product in every case being derived from insertion through the exo face.

Original languageEnglish (US)
Pages (from-to)5396-5398
Number of pages3
JournalOrganometallics
Volume23
Issue number23
DOIs
StatePublished - Nov 8 2004

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Palladium
Carboxylic Acids
carboxylic acids
Chlorides
palladium
esters
insertion
Esters
polymerization
Metals
chlorides
Polymerization
Derivatives
dienes
metals
acetates
products
2-norbornene
1,5-cyclooctadiene
methyl acetate

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

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abstract = "The insertions of norbornene, bicyclo[2.2.1]-hept-5-ene-endo-2-carboxylic acid ethyl ester, bicyclo-[2.2.1]hept-5-ene-exo-2-carboxylic acid ethyl ester, and bicyclo[2.2.1]hept-5-enyl-endo-2-methyl acetate into the palladium-methyl bond of(η 4-cycloocta-1,5-diene)chloromethylpalladium(II) were found to proceed at similar rates, with the product in every case being derived from insertion through the exo face.",
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T1 - Reaction of palladium 1,5-cyclooctadiene alkyl chloride with norbornene derivatives

T2 - Relevance to metal-catalyzed addition polymerization of functionalized norbornenes

AU - Kang, Myeongsoon

AU - Sen, Ayusman

PY - 2004/11/8

Y1 - 2004/11/8

N2 - The insertions of norbornene, bicyclo[2.2.1]-hept-5-ene-endo-2-carboxylic acid ethyl ester, bicyclo-[2.2.1]hept-5-ene-exo-2-carboxylic acid ethyl ester, and bicyclo[2.2.1]hept-5-enyl-endo-2-methyl acetate into the palladium-methyl bond of(η 4-cycloocta-1,5-diene)chloromethylpalladium(II) were found to proceed at similar rates, with the product in every case being derived from insertion through the exo face.

AB - The insertions of norbornene, bicyclo[2.2.1]-hept-5-ene-endo-2-carboxylic acid ethyl ester, bicyclo-[2.2.1]hept-5-ene-exo-2-carboxylic acid ethyl ester, and bicyclo[2.2.1]hept-5-enyl-endo-2-methyl acetate into the palladium-methyl bond of(η 4-cycloocta-1,5-diene)chloromethylpalladium(II) were found to proceed at similar rates, with the product in every case being derived from insertion through the exo face.

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