Reactions of 1,3-diaza-1,3-butadienes with haloketenes - rearrangements accompanying [4+2] cycloaddition reactions.

Sujit N. Mazumdar, Sucharita Mukherjee, Arun K. Sharma, Devashish Sengupta, Mohinder P. Mahajan

Research output: Contribution to journalArticlepeer-review

39 Scopus citations

Abstract

1-Aryl-2-phenyl-4-thioalkyl-4-secondaryamino-1,3-diaza-1, 3-butadienes 8 yielded interesting pyrimidones 10, 22 and 7 with chloroketenes 2, 11 and 12 through their episulfonium intermediates, whereas 1-aryl-2-phenyl-(methylthio) -4-dimethylamino-1,3-diaza-1,3-butadienes 1 give different pyrimidones with different haloketenes (chloro, bromo and iodo).

Original languageEnglish (US)
Pages (from-to)7579-7588
Number of pages10
JournalTetrahedron
Volume50
Issue number25
DOIs
StatePublished - 1994

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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