Reactive intermediate phase cold sintering in strontium titanate

R. Boston, J. Guo, S. Funahashi, A. L. Baker, I. M. Reaney, C. A. Randall

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

Dense (>96% theoretical) strontium titanate ceramics were fabricated at 950 °C (conventional sintering temperature > 1400 °C) using a reactive intermediate phase cold sintering process. An aqueous solution of SrCl2 mixed with TiO2 nanoparticles was added to SrTiO3 powders and pressed at 180 °C to obtain a highly compacted green body. During the post-press heating step at 950 °C, the TiO2 and SrCl2 create in-filling micro-reactions around each grain resulting in dense (>96%) SrTiO3 ceramics. Nano- and micron-sized starting powders were used, demonstrating that this reactive intermediate phase cold sintering route can densify a wide range of starting powder sizes, as it not reliant on an amorphous-to-crystalline precipitation through the terrace ledge kink mechanism, as has been identified repeatedly in previous cold sintering mechanisms. Moreover, this process has the potential to densify a wide variety of functional oxides, as a range of different low-temperature chemical synthesis routes could be used.

Original languageEnglish (US)
Pages (from-to)20372-20378
Number of pages7
JournalRSC Advances
Volume8
Issue number36
DOIs
StatePublished - Jan 1 2018

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

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