Reactive transport modeling of interactions between acid gas (CO 2 + H2S) and pozzolan-amended wellbore cement under geologic carbon sequestration conditions

Liwei Zhang, David A. Dzombak, David V. Nakles, Jean Patrick Leopold Brunet, Li Li

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

The implementation of acid gas cosequestration requires investigation of the potential for acid gas leakage along existing wellbores at sequestration sites. In this study, the interaction between pozzolan-amended wellbore cement (35 vol % pozzolan/65 vol % cement, hereafter referred to as 35:65 sample) and acid gas (e.g., a mixture of CO2 and H2S) was simulated using the reactive transport code CrunchFlow. The model was applied to describe, interpret, and extrapolate scanning electron microscopy-backscattered electron (SEM-BSE) and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) results on pozzolan-amended cement samples exposed to a 1 wt % NaCl solution saturated with an acid gas mixture of 21 mol % H2S and 79 mol % CO2 under the temperature of 50 °C and pressure of 150 bar. Simulation outputs included calcite volume percentage, total Ca and S weight percentages in the solid phase, porosity, and effective permeability from the surface to the interior of pozzolan-amended wellbore cement. The model reproduced the observed calcite zone formed in the brine-cement interface region of the sample after 2.5 days of exposure. The model also predicted that the calcite layer became dense (calcite vol % in the layer reached 55%) after 90 days of exposure, consistent with the experimental observation. C-S-H was the primary Ca2+ source to form the calcite layer, followed by C3S and Ca(OH)2. The main observed products of reaction between the 35:65 sample and H2S were pyrite and ettringite. Pyrite was primarily formed within 0.5 mm from the brine-cement interface; ettringite mainly formed within 1 mm from the interface. The model simulated these reactions that only the interface region (up to 2 mm distance from the surface) of the 35:65 sample became porous after 30 years of exposure. However, this narrow porous region could still serve as a migration pathway for acid gas, which was indicated by the increase in effective parallel permeability values determined from the simulation results. Those results show consistency with results of neat cement samples exposed under similar conditions. An increase in H2S content (in the range of 0 mol % to 40 mol %) results in more dissolution of Ca-bearing minerals in cement and more precipitation of calcite. Overall, this study indicates that an increase of porosity and permeability of pozzolan-amended wellbore cement at the cement interface with brine saturated with CO2 and H2S can cause significant changes in effective permeability of the cement.

Original languageEnglish (US)
Pages (from-to)6921-6937
Number of pages17
JournalEnergy and Fuels
Volume27
Issue number11
DOIs
StatePublished - Nov 21 2013

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Pozzolan
Carbon Monoxide
Cements
Carbon
Gases
Calcium Carbonate
Calcite
Acids
Pyrites
Bearings (structural)
Porosity
Interiors (building)
Scanning electron microscopy
Leakage (fluid)
Gas mixtures
Minerals
Energy dispersive spectroscopy
Dissolution

All Science Journal Classification (ASJC) codes

  • Chemical Engineering(all)
  • Fuel Technology
  • Energy Engineering and Power Technology

Cite this

Zhang, Liwei ; Dzombak, David A. ; Nakles, David V. ; Brunet, Jean Patrick Leopold ; Li, Li. / Reactive transport modeling of interactions between acid gas (CO 2 + H2S) and pozzolan-amended wellbore cement under geologic carbon sequestration conditions. In: Energy and Fuels. 2013 ; Vol. 27, No. 11. pp. 6921-6937.
@article{319cba81de7c40ccb6d9ae3eacc7797c,
title = "Reactive transport modeling of interactions between acid gas (CO 2 + H2S) and pozzolan-amended wellbore cement under geologic carbon sequestration conditions",
abstract = "The implementation of acid gas cosequestration requires investigation of the potential for acid gas leakage along existing wellbores at sequestration sites. In this study, the interaction between pozzolan-amended wellbore cement (35 vol {\%} pozzolan/65 vol {\%} cement, hereafter referred to as 35:65 sample) and acid gas (e.g., a mixture of CO2 and H2S) was simulated using the reactive transport code CrunchFlow. The model was applied to describe, interpret, and extrapolate scanning electron microscopy-backscattered electron (SEM-BSE) and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) results on pozzolan-amended cement samples exposed to a 1 wt {\%} NaCl solution saturated with an acid gas mixture of 21 mol {\%} H2S and 79 mol {\%} CO2 under the temperature of 50 °C and pressure of 150 bar. Simulation outputs included calcite volume percentage, total Ca and S weight percentages in the solid phase, porosity, and effective permeability from the surface to the interior of pozzolan-amended wellbore cement. The model reproduced the observed calcite zone formed in the brine-cement interface region of the sample after 2.5 days of exposure. The model also predicted that the calcite layer became dense (calcite vol {\%} in the layer reached 55{\%}) after 90 days of exposure, consistent with the experimental observation. C-S-H was the primary Ca2+ source to form the calcite layer, followed by C3S and Ca(OH)2. The main observed products of reaction between the 35:65 sample and H2S were pyrite and ettringite. Pyrite was primarily formed within 0.5 mm from the brine-cement interface; ettringite mainly formed within 1 mm from the interface. The model simulated these reactions that only the interface region (up to 2 mm distance from the surface) of the 35:65 sample became porous after 30 years of exposure. However, this narrow porous region could still serve as a migration pathway for acid gas, which was indicated by the increase in effective parallel permeability values determined from the simulation results. Those results show consistency with results of neat cement samples exposed under similar conditions. An increase in H2S content (in the range of 0 mol {\%} to 40 mol {\%}) results in more dissolution of Ca-bearing minerals in cement and more precipitation of calcite. Overall, this study indicates that an increase of porosity and permeability of pozzolan-amended wellbore cement at the cement interface with brine saturated with CO2 and H2S can cause significant changes in effective permeability of the cement.",
author = "Liwei Zhang and Dzombak, {David A.} and Nakles, {David V.} and Brunet, {Jean Patrick Leopold} and Li Li",
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Reactive transport modeling of interactions between acid gas (CO 2 + H2S) and pozzolan-amended wellbore cement under geologic carbon sequestration conditions. / Zhang, Liwei; Dzombak, David A.; Nakles, David V.; Brunet, Jean Patrick Leopold; Li, Li.

In: Energy and Fuels, Vol. 27, No. 11, 21.11.2013, p. 6921-6937.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Reactive transport modeling of interactions between acid gas (CO 2 + H2S) and pozzolan-amended wellbore cement under geologic carbon sequestration conditions

AU - Zhang, Liwei

AU - Dzombak, David A.

AU - Nakles, David V.

AU - Brunet, Jean Patrick Leopold

AU - Li, Li

PY - 2013/11/21

Y1 - 2013/11/21

N2 - The implementation of acid gas cosequestration requires investigation of the potential for acid gas leakage along existing wellbores at sequestration sites. In this study, the interaction between pozzolan-amended wellbore cement (35 vol % pozzolan/65 vol % cement, hereafter referred to as 35:65 sample) and acid gas (e.g., a mixture of CO2 and H2S) was simulated using the reactive transport code CrunchFlow. The model was applied to describe, interpret, and extrapolate scanning electron microscopy-backscattered electron (SEM-BSE) and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) results on pozzolan-amended cement samples exposed to a 1 wt % NaCl solution saturated with an acid gas mixture of 21 mol % H2S and 79 mol % CO2 under the temperature of 50 °C and pressure of 150 bar. Simulation outputs included calcite volume percentage, total Ca and S weight percentages in the solid phase, porosity, and effective permeability from the surface to the interior of pozzolan-amended wellbore cement. The model reproduced the observed calcite zone formed in the brine-cement interface region of the sample after 2.5 days of exposure. The model also predicted that the calcite layer became dense (calcite vol % in the layer reached 55%) after 90 days of exposure, consistent with the experimental observation. C-S-H was the primary Ca2+ source to form the calcite layer, followed by C3S and Ca(OH)2. The main observed products of reaction between the 35:65 sample and H2S were pyrite and ettringite. Pyrite was primarily formed within 0.5 mm from the brine-cement interface; ettringite mainly formed within 1 mm from the interface. The model simulated these reactions that only the interface region (up to 2 mm distance from the surface) of the 35:65 sample became porous after 30 years of exposure. However, this narrow porous region could still serve as a migration pathway for acid gas, which was indicated by the increase in effective parallel permeability values determined from the simulation results. Those results show consistency with results of neat cement samples exposed under similar conditions. An increase in H2S content (in the range of 0 mol % to 40 mol %) results in more dissolution of Ca-bearing minerals in cement and more precipitation of calcite. Overall, this study indicates that an increase of porosity and permeability of pozzolan-amended wellbore cement at the cement interface with brine saturated with CO2 and H2S can cause significant changes in effective permeability of the cement.

AB - The implementation of acid gas cosequestration requires investigation of the potential for acid gas leakage along existing wellbores at sequestration sites. In this study, the interaction between pozzolan-amended wellbore cement (35 vol % pozzolan/65 vol % cement, hereafter referred to as 35:65 sample) and acid gas (e.g., a mixture of CO2 and H2S) was simulated using the reactive transport code CrunchFlow. The model was applied to describe, interpret, and extrapolate scanning electron microscopy-backscattered electron (SEM-BSE) and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS) results on pozzolan-amended cement samples exposed to a 1 wt % NaCl solution saturated with an acid gas mixture of 21 mol % H2S and 79 mol % CO2 under the temperature of 50 °C and pressure of 150 bar. Simulation outputs included calcite volume percentage, total Ca and S weight percentages in the solid phase, porosity, and effective permeability from the surface to the interior of pozzolan-amended wellbore cement. The model reproduced the observed calcite zone formed in the brine-cement interface region of the sample after 2.5 days of exposure. The model also predicted that the calcite layer became dense (calcite vol % in the layer reached 55%) after 90 days of exposure, consistent with the experimental observation. C-S-H was the primary Ca2+ source to form the calcite layer, followed by C3S and Ca(OH)2. The main observed products of reaction between the 35:65 sample and H2S were pyrite and ettringite. Pyrite was primarily formed within 0.5 mm from the brine-cement interface; ettringite mainly formed within 1 mm from the interface. The model simulated these reactions that only the interface region (up to 2 mm distance from the surface) of the 35:65 sample became porous after 30 years of exposure. However, this narrow porous region could still serve as a migration pathway for acid gas, which was indicated by the increase in effective parallel permeability values determined from the simulation results. Those results show consistency with results of neat cement samples exposed under similar conditions. An increase in H2S content (in the range of 0 mol % to 40 mol %) results in more dissolution of Ca-bearing minerals in cement and more precipitation of calcite. Overall, this study indicates that an increase of porosity and permeability of pozzolan-amended wellbore cement at the cement interface with brine saturated with CO2 and H2S can cause significant changes in effective permeability of the cement.

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