Recent advances in Co-based co-catalysts for efficient photocatalytic hydrogen generation

Recent progress in photocatalytic hydrogen generation reaction highlights the critical role of co-catalysts in enhancing the solar-to-fuel conversion efficiency of diverse band-matched semiconductors. Because of the compositional flexibility, adjustable microstructure, tunable crystal phase and facet, cobalt-based co-catalysts have stimulated tremendous attention as they have high potential to promote hydrogen evolution reaction. However, a comprehensive review that specifically focuses on these promising materials has not been reported so far. Therefore, this present review emphasizes the recent progress in the pursuing of highly efficient Co-based co-catalysts for water splitting, and the advances in such materials are summarized through the analysis of structure–activity relationships. The fundamental principles of photocatalytic hydrogen production are profoundly outlined, followed by an elaborate discussion on the crucial parameters influencing the reaction kinetics. Then, the co-catalytic reactivities of various Co-based materials involving Co, Co oxides, Co hydroxides, Co sulfides, Co phosphides and Co molecular complexes, etc, are thoroughly discussed when they are coupled with host semiconductors, with an insight towards the ultimate objective of achieving a rationally designed photocatalyst for enhancing water splitting reaction dynamics. Finally, the current challenge and future perspective of Co-based co-catalysts as the promising noble-metal alternative materials for solar hydrogen generation are proposed and discussed.