TY - JOUR
T1 - Reductive Removal of Four Halogenated Organic Compounds by Different Sizes of Zero-Valent-Iron
AU - Zhao, Xufei
AU - Wei, Caijie
AU - Zhang, Jin
AU - Wu, Weizhong
AU - Wang, Xiaomao
AU - Yang, Hongwei
AU - Xie, Yuefeng
PY - 2018/3/20
Y1 - 2018/3/20
N2 - Based on the chlorinated organic compounds pollution existed in underground water of China, Zero-Valent-Iron (ZVI) technology is employed for the removal of four representative halogenated organic compounds (HOCs) (tetrachloroethylene, PCE; tricholoroethylene, TCE; tetrachlormethane, TCM; and chloroform, CT). The results indicated that the reduction rates of four target compounds, of which the initial concentration is 400 μg/L, negatively correlated with the size of Zero-Valent-Iron particles. The reduction kinetics of the targeted HOCs were all well fitted with the Pseudo-firstorder kinetics, and the ranking of obtained first order rate constants (K) among different particle sizes was K 20nm >K 100nm >K 10μm >K 100μm . Comparing K among four target HOCs, the reduction rates of chlorinated methane (CT, TCM) are higher than chlorinated ethylene (PCE, TCE), and highly chlorinated HOCs (PCE, CT) were degraded more easily than lower one (TCE, TCM). pH of aqueous solution all increased along the chlorinated compounds reduction which was raised by the reaction between ZVI and water. The oxygen in water consumed the ZVI particle either and competed with the surface adsorbed chlorinated compounds. In summary, Zero-Valent-Iron proved to be an efficient technology for typical HOCs removal, which can be considered as a promising process added in the beginning part of drinking water treatment plant.
AB - Based on the chlorinated organic compounds pollution existed in underground water of China, Zero-Valent-Iron (ZVI) technology is employed for the removal of four representative halogenated organic compounds (HOCs) (tetrachloroethylene, PCE; tricholoroethylene, TCE; tetrachlormethane, TCM; and chloroform, CT). The results indicated that the reduction rates of four target compounds, of which the initial concentration is 400 μg/L, negatively correlated with the size of Zero-Valent-Iron particles. The reduction kinetics of the targeted HOCs were all well fitted with the Pseudo-firstorder kinetics, and the ranking of obtained first order rate constants (K) among different particle sizes was K 20nm >K 100nm >K 10μm >K 100μm . Comparing K among four target HOCs, the reduction rates of chlorinated methane (CT, TCM) are higher than chlorinated ethylene (PCE, TCE), and highly chlorinated HOCs (PCE, CT) were degraded more easily than lower one (TCE, TCM). pH of aqueous solution all increased along the chlorinated compounds reduction which was raised by the reaction between ZVI and water. The oxygen in water consumed the ZVI particle either and competed with the surface adsorbed chlorinated compounds. In summary, Zero-Valent-Iron proved to be an efficient technology for typical HOCs removal, which can be considered as a promising process added in the beginning part of drinking water treatment plant.
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U2 - 10.13209/j.0479-8023.2017.165
DO - 10.13209/j.0479-8023.2017.165
M3 - Article
AN - SCOPUS:85048002269
VL - 54
SP - 435
EP - 442
JO - Beijing Daxue Xuebao (Ziran Kexue Ban)/Acta Scientiarum Naturalium Universitatis Pekinensis
JF - Beijing Daxue Xuebao (Ziran Kexue Ban)/Acta Scientiarum Naturalium Universitatis Pekinensis
SN - 0479-8023
IS - 2
ER -