Regulation of micromorphology and proton conductivity of sulfonated polyimide/crosslinked PNIPAm semi-interpenetrating networks by hydrogen bonding

Yao He, Lei Geng, Cuiyan Tong, Lingdi Liu, Changli Lü

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

The hydrogen bond interaction between cPNIPAm and SPI in the semi-IPN structure is a crucial factor for regulating the micromorphology and properties of the semi-IPN proton exchange membranes. A series of novel sulfonated polyimide (SPI)/crosslinked poly(N-isopropylacrylamide) (cPNIPAm) semi-interpenetrating polymer networks (semi-IPNs) were synthesized as the proton exchange membranes for direct methanol fuel cells via in situ polymerization. The micromorphology and properties of the semi-IPN membranes were characterized. The results indicated that the hydrogen bonds between cPNIPAm and SPI in the semi-IPN structure were a crucial factor for regulating the micromorphology, proton conductivity and other properties of the semi-IPN membranes. A more uniform sulfonic ionic cluster distribution was observed in the membrane of SPI-20-cPNIPAm with equimolar ratio of sulfonic acid groups and amido bonds, which could provide effective proton transport channels. The SPI-20-cPNIPAm exhibited a maximum proton conductivity of 0.331Scm-1 at 80 oC (relative humidity 100%), an optimal selectivity of 8.01×105Sscm-3 and an improved fuel cell performance of 72 mW cm-2 compared with both pristine SPI and other semi-IPN membranes. The SPI-20-cPNIPAm semi-IPN membranes also retained good mechanical properties and thermal stabilities on the whole.

Original languageEnglish (US)
Pages (from-to)1806-1815
Number of pages10
JournalPolymer International
Volume63
Issue number10
DOIs
StatePublished - Oct 1 2014

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Interpenetrating polymer networks
Proton conductivity
Polyimides
Hydrogen bonds
Membranes
Protons
Ion exchange
Sulfonic Acids
Direct methanol fuel cells (DMFC)
poly-N-isopropylacrylamide
Fuel cells
Atmospheric humidity
Thermodynamic stability
Polymerization
Mechanical properties
Acids

All Science Journal Classification (ASJC) codes

  • Polymers and Plastics
  • Organic Chemistry
  • Materials Chemistry

Cite this

He, Yao ; Geng, Lei ; Tong, Cuiyan ; Liu, Lingdi ; Lü, Changli. / Regulation of micromorphology and proton conductivity of sulfonated polyimide/crosslinked PNIPAm semi-interpenetrating networks by hydrogen bonding. In: Polymer International. 2014 ; Vol. 63, No. 10. pp. 1806-1815.
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abstract = "The hydrogen bond interaction between cPNIPAm and SPI in the semi-IPN structure is a crucial factor for regulating the micromorphology and properties of the semi-IPN proton exchange membranes. A series of novel sulfonated polyimide (SPI)/crosslinked poly(N-isopropylacrylamide) (cPNIPAm) semi-interpenetrating polymer networks (semi-IPNs) were synthesized as the proton exchange membranes for direct methanol fuel cells via in situ polymerization. The micromorphology and properties of the semi-IPN membranes were characterized. The results indicated that the hydrogen bonds between cPNIPAm and SPI in the semi-IPN structure were a crucial factor for regulating the micromorphology, proton conductivity and other properties of the semi-IPN membranes. A more uniform sulfonic ionic cluster distribution was observed in the membrane of SPI-20-cPNIPAm with equimolar ratio of sulfonic acid groups and amido bonds, which could provide effective proton transport channels. The SPI-20-cPNIPAm exhibited a maximum proton conductivity of 0.331Scm-1 at 80 oC (relative humidity 100{\%}), an optimal selectivity of 8.01×105Sscm-3 and an improved fuel cell performance of 72 mW cm-2 compared with both pristine SPI and other semi-IPN membranes. The SPI-20-cPNIPAm semi-IPN membranes also retained good mechanical properties and thermal stabilities on the whole.",
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Regulation of micromorphology and proton conductivity of sulfonated polyimide/crosslinked PNIPAm semi-interpenetrating networks by hydrogen bonding. / He, Yao; Geng, Lei; Tong, Cuiyan; Liu, Lingdi; Lü, Changli.

In: Polymer International, Vol. 63, No. 10, 01.10.2014, p. 1806-1815.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Regulation of micromorphology and proton conductivity of sulfonated polyimide/crosslinked PNIPAm semi-interpenetrating networks by hydrogen bonding

AU - He, Yao

AU - Geng, Lei

AU - Tong, Cuiyan

AU - Liu, Lingdi

AU - Lü, Changli

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N2 - The hydrogen bond interaction between cPNIPAm and SPI in the semi-IPN structure is a crucial factor for regulating the micromorphology and properties of the semi-IPN proton exchange membranes. A series of novel sulfonated polyimide (SPI)/crosslinked poly(N-isopropylacrylamide) (cPNIPAm) semi-interpenetrating polymer networks (semi-IPNs) were synthesized as the proton exchange membranes for direct methanol fuel cells via in situ polymerization. The micromorphology and properties of the semi-IPN membranes were characterized. The results indicated that the hydrogen bonds between cPNIPAm and SPI in the semi-IPN structure were a crucial factor for regulating the micromorphology, proton conductivity and other properties of the semi-IPN membranes. A more uniform sulfonic ionic cluster distribution was observed in the membrane of SPI-20-cPNIPAm with equimolar ratio of sulfonic acid groups and amido bonds, which could provide effective proton transport channels. The SPI-20-cPNIPAm exhibited a maximum proton conductivity of 0.331Scm-1 at 80 oC (relative humidity 100%), an optimal selectivity of 8.01×105Sscm-3 and an improved fuel cell performance of 72 mW cm-2 compared with both pristine SPI and other semi-IPN membranes. The SPI-20-cPNIPAm semi-IPN membranes also retained good mechanical properties and thermal stabilities on the whole.

AB - The hydrogen bond interaction between cPNIPAm and SPI in the semi-IPN structure is a crucial factor for regulating the micromorphology and properties of the semi-IPN proton exchange membranes. A series of novel sulfonated polyimide (SPI)/crosslinked poly(N-isopropylacrylamide) (cPNIPAm) semi-interpenetrating polymer networks (semi-IPNs) were synthesized as the proton exchange membranes for direct methanol fuel cells via in situ polymerization. The micromorphology and properties of the semi-IPN membranes were characterized. The results indicated that the hydrogen bonds between cPNIPAm and SPI in the semi-IPN structure were a crucial factor for regulating the micromorphology, proton conductivity and other properties of the semi-IPN membranes. A more uniform sulfonic ionic cluster distribution was observed in the membrane of SPI-20-cPNIPAm with equimolar ratio of sulfonic acid groups and amido bonds, which could provide effective proton transport channels. The SPI-20-cPNIPAm exhibited a maximum proton conductivity of 0.331Scm-1 at 80 oC (relative humidity 100%), an optimal selectivity of 8.01×105Sscm-3 and an improved fuel cell performance of 72 mW cm-2 compared with both pristine SPI and other semi-IPN membranes. The SPI-20-cPNIPAm semi-IPN membranes also retained good mechanical properties and thermal stabilities on the whole.

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