Responsive macroscopic materials from self-assembled cross-linked SiO 2-PNIPAAm core/shell structures

Christian Pester, Artjom Konradi, Birte Varnholt, Patrick Van Rijn, Alexander Böker

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

A way to obtain macroscopic responsive materials from silicon-oxide polymer core/shell microstructures is presented. The microparticles are composed of a 60 nm SiO 2-core with a random copolymer corona of the temperature responsive poly-N-isopropylacrylamide (PNIPAAm) and the UV-cross-linkable 2-(dimethyl maleinimido)-N-ethyl-acrylamide. The particles shrink upon heating and form a stable gel in both water and tetrahydrofuran (THF) at 3-5 wt% particle content. Cross-linking the aqueous gel results in shrinkage when the temperature is increased above the lower critical solution temperature and it regains its original size upon cooling. By freeze drying with subsequent UV irradiation, thin stable layers are prepared. Stable fibers are produced by extruding a THF gel into water and subsequent UV irradiation, harnessing the cononsolvency effect of PNIPAAm in water/THF mixtures. The temperature responsiveness translates to the macroscopic materials as both films and fibers show the same collapsing behavior as the microcore/shell particle. The collapse and re-swelling of the materials is related to the expelling and re-uptake of water, which is used to incorporate gold nanoparticles into the materials by a simple heating/cooling cycle. This allows for future applications, as various functional particles (antibacterial, fluorescence, catalysis, etc.) can easily be incorporated in these systems.

Original languageEnglish (US)
Pages (from-to)1724-1731
Number of pages8
JournalAdvanced Functional Materials
Volume22
Issue number8
DOIs
StatePublished - Apr 24 2012

Fingerprint

tetrahydrofuran
Gels
Water
gels
water
Particles (particulate matter)
Irradiation
extruding
Cooling
cooling
Heating
freeze drying
Temperature
Regain
irradiation
heating
fibers
temperature
Acrylamide
Fibers

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Condensed Matter Physics
  • Electrochemistry

Cite this

Pester, Christian ; Konradi, Artjom ; Varnholt, Birte ; Van Rijn, Patrick ; Böker, Alexander. / Responsive macroscopic materials from self-assembled cross-linked SiO 2-PNIPAAm core/shell structures. In: Advanced Functional Materials. 2012 ; Vol. 22, No. 8. pp. 1724-1731.
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Responsive macroscopic materials from self-assembled cross-linked SiO 2-PNIPAAm core/shell structures. / Pester, Christian; Konradi, Artjom; Varnholt, Birte; Van Rijn, Patrick; Böker, Alexander.

In: Advanced Functional Materials, Vol. 22, No. 8, 24.04.2012, p. 1724-1731.

Research output: Contribution to journalArticle

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