Roll-to-roll fabrication of high surface area mesoporous carbon with process-tunable pore texture for optimization of adsorption capacity of bulky organic dyes

Zhe Qiang, Burcu Gurkan, Jianxing Ma, Xiangyu Liu, Yuanhao Guo, Miko Cakmak, Kevin A. Cavicchi, Bryan D. Vogt

Research output: Contribution to journalArticle

20 Citations (Scopus)

Abstract

Large-scale (multigram-to-kilogram) fabrication of soft-templated ordered mesoporous carbon (OMC) is enabled by roll-to-roll (R2R) processing via evaporation induced self assembly of Pluronic F127, oligomeric phenolic resin (resol), and tetraorthosilicate (TEOS) from ethanolic solution. The solution concentration, TEOS loading (etchable for microporous framework), and crosslinking temperature impact the pore structure. Here we demonstrate that mesoporous carbons with surface areas up to 2455 m2/g can be obtained under the proper processing conditions. Transmission electron microscopy (TEM), small-angle X-ray scattering (SAXS) and nitrogen adsorption-desorption isotherms reveal (i) suppressed framework shrinkage with increasing solution concentration during casting, (ii) improved long range order and higher surface area with increasing TEOS content up to 3:1 TEOS:resol, and (iii) enhanced porosity with crosslinking at 100°C. These differences can be explained on the basis of block copolymer thermodynamics and mechanical reinforcement by silica. This family of OMCs are effective adsorbents for bulky aqueous organic dyes, such as methylene green (MG) and methyl blue (MB), with high adsorption capacities of 0.436 g MG/g OMC and 0.378 g MB/g OMC obtained. This R2R method provides a facile method to generate significant quantities of OMCs with tunable pore textures.

Original languageEnglish (US)
Pages (from-to)57-64
Number of pages8
JournalMicroporous and Mesoporous Materials
Volume227
DOIs
StatePublished - Jun 2016

Fingerprint

Coloring Agents
Carbon
Dyes
textures
Textures
dyes
porosity
Adsorption
Fabrication
fabrication
UCON 50-HB-5100
optimization
adsorption
carbon
crosslinking
methylene
Crosslinking
phenolic resins
Poloxamer
Phenolic resins

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials

Cite this

Qiang, Zhe ; Gurkan, Burcu ; Ma, Jianxing ; Liu, Xiangyu ; Guo, Yuanhao ; Cakmak, Miko ; Cavicchi, Kevin A. ; Vogt, Bryan D. / Roll-to-roll fabrication of high surface area mesoporous carbon with process-tunable pore texture for optimization of adsorption capacity of bulky organic dyes. In: Microporous and Mesoporous Materials. 2016 ; Vol. 227. pp. 57-64.
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abstract = "Large-scale (multigram-to-kilogram) fabrication of soft-templated ordered mesoporous carbon (OMC) is enabled by roll-to-roll (R2R) processing via evaporation induced self assembly of Pluronic F127, oligomeric phenolic resin (resol), and tetraorthosilicate (TEOS) from ethanolic solution. The solution concentration, TEOS loading (etchable for microporous framework), and crosslinking temperature impact the pore structure. Here we demonstrate that mesoporous carbons with surface areas up to 2455 m2/g can be obtained under the proper processing conditions. Transmission electron microscopy (TEM), small-angle X-ray scattering (SAXS) and nitrogen adsorption-desorption isotherms reveal (i) suppressed framework shrinkage with increasing solution concentration during casting, (ii) improved long range order and higher surface area with increasing TEOS content up to 3:1 TEOS:resol, and (iii) enhanced porosity with crosslinking at 100°C. These differences can be explained on the basis of block copolymer thermodynamics and mechanical reinforcement by silica. This family of OMCs are effective adsorbents for bulky aqueous organic dyes, such as methylene green (MG) and methyl blue (MB), with high adsorption capacities of 0.436 g MG/g OMC and 0.378 g MB/g OMC obtained. This R2R method provides a facile method to generate significant quantities of OMCs with tunable pore textures.",
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Roll-to-roll fabrication of high surface area mesoporous carbon with process-tunable pore texture for optimization of adsorption capacity of bulky organic dyes. / Qiang, Zhe; Gurkan, Burcu; Ma, Jianxing; Liu, Xiangyu; Guo, Yuanhao; Cakmak, Miko; Cavicchi, Kevin A.; Vogt, Bryan D.

In: Microporous and Mesoporous Materials, Vol. 227, 06.2016, p. 57-64.

Research output: Contribution to journalArticle

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T1 - Roll-to-roll fabrication of high surface area mesoporous carbon with process-tunable pore texture for optimization of adsorption capacity of bulky organic dyes

AU - Qiang, Zhe

AU - Gurkan, Burcu

AU - Ma, Jianxing

AU - Liu, Xiangyu

AU - Guo, Yuanhao

AU - Cakmak, Miko

AU - Cavicchi, Kevin A.

AU - Vogt, Bryan D.

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