Scalable Polymer Nanocomposites with Record High-Temperature Capacitive Performance Enabled by Rationally Designed Nanostructured Inorganic Fillers

He Li, Ding Ai, Lulu Ren, Bin Yao, Zhubing Han, Zhonghui Shen, Jianjun Wang, Long-qing Chen, Qing Wang

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Next-generation microelectronics and electrical power systems call for high-energy-density dielectric polymeric materials that can operate efficiently under elevated temperatures. However, the currently available polymer dielectrics are limited to relatively low working temperatures. Here, the solution-processable polymer nanocomposites consisting of readily prepared Al2O3 fillers with systematically varied morphologies including nanoparticles, nanowires, and nanoplates are reported. The field-dependent electrical conduction of the polymer nanocomposites at elevated temperatures is investigated. A strong dependence of the conduction behavior and breakdown strength of the polymer composites on the filler morphology is revealed experimentally and is further rationalized via computations. The polymer composites containing Al2O3 nanoplates display a record capacitive performance, e.g., a discharged energy density of 3.31 J cm−3 and a charge–discharge efficiency of >90% measured at 450 MV m−1 and 150 °C, significantly outperforming the state-of-the-art dielectric polymers and nanocomposites that are typically prepared via tedious, low-yield approaches.

Original languageEnglish (US)
Article number1900875
JournalAdvanced Materials
Volume31
Issue number23
DOIs
StatePublished - Jun 6 2019

Fingerprint

Fillers
Nanocomposites
Polymers
Temperature
Composite materials
Polymer solutions
Microelectronics
Nanowires
Nanoparticles

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

@article{054a11deaad6495f9aa183d6c7fc007f,
title = "Scalable Polymer Nanocomposites with Record High-Temperature Capacitive Performance Enabled by Rationally Designed Nanostructured Inorganic Fillers",
abstract = "Next-generation microelectronics and electrical power systems call for high-energy-density dielectric polymeric materials that can operate efficiently under elevated temperatures. However, the currently available polymer dielectrics are limited to relatively low working temperatures. Here, the solution-processable polymer nanocomposites consisting of readily prepared Al2O3 fillers with systematically varied morphologies including nanoparticles, nanowires, and nanoplates are reported. The field-dependent electrical conduction of the polymer nanocomposites at elevated temperatures is investigated. A strong dependence of the conduction behavior and breakdown strength of the polymer composites on the filler morphology is revealed experimentally and is further rationalized via computations. The polymer composites containing Al2O3 nanoplates display a record capacitive performance, e.g., a discharged energy density of 3.31 J cm−3 and a charge–discharge efficiency of >90{\%} measured at 450 MV m−1 and 150 °C, significantly outperforming the state-of-the-art dielectric polymers and nanocomposites that are typically prepared via tedious, low-yield approaches.",
author = "He Li and Ding Ai and Lulu Ren and Bin Yao and Zhubing Han and Zhonghui Shen and Jianjun Wang and Long-qing Chen and Qing Wang",
year = "2019",
month = "6",
day = "6",
doi = "10.1002/adma.201900875",
language = "English (US)",
volume = "31",
journal = "Advanced Materials",
issn = "0935-9648",
publisher = "Wiley-VCH Verlag",
number = "23",

}

Scalable Polymer Nanocomposites with Record High-Temperature Capacitive Performance Enabled by Rationally Designed Nanostructured Inorganic Fillers. / Li, He; Ai, Ding; Ren, Lulu; Yao, Bin; Han, Zhubing; Shen, Zhonghui; Wang, Jianjun; Chen, Long-qing; Wang, Qing.

In: Advanced Materials, Vol. 31, No. 23, 1900875, 06.06.2019.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Scalable Polymer Nanocomposites with Record High-Temperature Capacitive Performance Enabled by Rationally Designed Nanostructured Inorganic Fillers

AU - Li, He

AU - Ai, Ding

AU - Ren, Lulu

AU - Yao, Bin

AU - Han, Zhubing

AU - Shen, Zhonghui

AU - Wang, Jianjun

AU - Chen, Long-qing

AU - Wang, Qing

PY - 2019/6/6

Y1 - 2019/6/6

N2 - Next-generation microelectronics and electrical power systems call for high-energy-density dielectric polymeric materials that can operate efficiently under elevated temperatures. However, the currently available polymer dielectrics are limited to relatively low working temperatures. Here, the solution-processable polymer nanocomposites consisting of readily prepared Al2O3 fillers with systematically varied morphologies including nanoparticles, nanowires, and nanoplates are reported. The field-dependent electrical conduction of the polymer nanocomposites at elevated temperatures is investigated. A strong dependence of the conduction behavior and breakdown strength of the polymer composites on the filler morphology is revealed experimentally and is further rationalized via computations. The polymer composites containing Al2O3 nanoplates display a record capacitive performance, e.g., a discharged energy density of 3.31 J cm−3 and a charge–discharge efficiency of >90% measured at 450 MV m−1 and 150 °C, significantly outperforming the state-of-the-art dielectric polymers and nanocomposites that are typically prepared via tedious, low-yield approaches.

AB - Next-generation microelectronics and electrical power systems call for high-energy-density dielectric polymeric materials that can operate efficiently under elevated temperatures. However, the currently available polymer dielectrics are limited to relatively low working temperatures. Here, the solution-processable polymer nanocomposites consisting of readily prepared Al2O3 fillers with systematically varied morphologies including nanoparticles, nanowires, and nanoplates are reported. The field-dependent electrical conduction of the polymer nanocomposites at elevated temperatures is investigated. A strong dependence of the conduction behavior and breakdown strength of the polymer composites on the filler morphology is revealed experimentally and is further rationalized via computations. The polymer composites containing Al2O3 nanoplates display a record capacitive performance, e.g., a discharged energy density of 3.31 J cm−3 and a charge–discharge efficiency of >90% measured at 450 MV m−1 and 150 °C, significantly outperforming the state-of-the-art dielectric polymers and nanocomposites that are typically prepared via tedious, low-yield approaches.

UR - http://www.scopus.com/inward/record.url?scp=85064443423&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85064443423&partnerID=8YFLogxK

U2 - 10.1002/adma.201900875

DO - 10.1002/adma.201900875

M3 - Article

C2 - 30977229

AN - SCOPUS:85064443423

VL - 31

JO - Advanced Materials

JF - Advanced Materials

SN - 0935-9648

IS - 23

M1 - 1900875

ER -