Self-assembled diode junctions prepared from a ruthenium tris(bipyridyl) polymer, n-type TiO2 nanoparticles, and graphite oxide sheets

Thierry Cassagneau; Janos H. Fendler; Stacy A. Johnson; Thomas E. Mallouk

doi:10.1002/1521-4095(200009)12:18<1363::AID-ADMA1363>3.0.CO;2-M

Self-assembled diode junctions prepared from a ruthenium tris(bipyridyl) polymer, n-type TiO₂ nanoparticles, and graphite oxide sheets

Thierry Cassagneau, Janos H. Fendler, Stacy A. Johnson, Thomas E. Mallouk

Research output: Contribution to journal › Article › peer-review

64 Citations (SciVal)

Abstract

The application of TiO₂ nanoparticles and graphite oxides (GO) nanoplatelets as electron- and hole-conducting components of such diodes was investigated. The rectifying properties of the films depended on the choice and sequence of components. Results showed that GO formed a rectifying junction with TiO₂ and acted as a charge compensating layer for layers of the [Ru(bpy)₃]⁺-containing polymer RuP. The conductance of RuP-containing thin-film devices prepared from GO was substantially higher than those containing polystyrene sulfonate, which formed resistive multilayer devices with RuP.

Original language	English (US)
Pages (from-to)	1363-1366
Number of pages	4
Journal	Advanced Materials
Volume	12
Issue number	18
DOIs	https://doi.org/10.1002/1521-4095(200009)12:18<1363::AID-ADMA1363>3.0.CO;2-M
State	Published - Sep 15 2000

All Science Journal Classification (ASJC) codes

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

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10.1002/1521-4095(200009)12:18<1363::AID-ADMA1363>3.0.CO;2-M

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title = "Self-assembled diode junctions prepared from a ruthenium tris(bipyridyl) polymer, n-type TiO2 nanoparticles, and graphite oxide sheets",

abstract = "The application of TiO2 nanoparticles and graphite oxides (GO) nanoplatelets as electron- and hole-conducting components of such diodes was investigated. The rectifying properties of the films depended on the choice and sequence of components. Results showed that GO formed a rectifying junction with TiO2 and acted as a charge compensating layer for layers of the [Ru(bpy)3]+-containing polymer RuP. The conductance of RuP-containing thin-film devices prepared from GO was substantially higher than those containing polystyrene sulfonate, which formed resistive multilayer devices with RuP.",

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T1 - Self-assembled diode junctions prepared from a ruthenium tris(bipyridyl) polymer, n-type TiO2 nanoparticles, and graphite oxide sheets

AU - Cassagneau, Thierry

AU - Fendler, Janos H.

AU - Johnson, Stacy A.

AU - Mallouk, Thomas E.

PY - 2000/9/15

Y1 - 2000/9/15

N2 - The application of TiO2 nanoparticles and graphite oxides (GO) nanoplatelets as electron- and hole-conducting components of such diodes was investigated. The rectifying properties of the films depended on the choice and sequence of components. Results showed that GO formed a rectifying junction with TiO2 and acted as a charge compensating layer for layers of the [Ru(bpy)3]+-containing polymer RuP. The conductance of RuP-containing thin-film devices prepared from GO was substantially higher than those containing polystyrene sulfonate, which formed resistive multilayer devices with RuP.

AB - The application of TiO2 nanoparticles and graphite oxides (GO) nanoplatelets as electron- and hole-conducting components of such diodes was investigated. The rectifying properties of the films depended on the choice and sequence of components. Results showed that GO formed a rectifying junction with TiO2 and acted as a charge compensating layer for layers of the [Ru(bpy)3]+-containing polymer RuP. The conductance of RuP-containing thin-film devices prepared from GO was substantially higher than those containing polystyrene sulfonate, which formed resistive multilayer devices with RuP.

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Self-assembled diode junctions prepared from a ruthenium tris(bipyridyl) polymer, n-type TiO₂ nanoparticles, and graphite oxide sheets

Abstract

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