Simplified chemical-physical theory for liquid metal solutions-I. Temperature dependence of the gibbs energy

Montgomery M. Alger, Charles A. Eckert

Research output: Contribution to journalArticle

6 Scopus citations

Abstract

The thermodynamic functions of Group IIB-VA systems Cd-Bi, Cd-Sb and Zn-Sb are modelled with a simplified chemical-physical theory model. Positive and negative deviations from ideal mixing behaviour are calculated with the model. Compounds of fixed stoichiometry are assumed in the liquid phase, with interatomic interactions represented by the Scatchard equation. Expressions for the enthalpy of mixing and mixture heat capacity are derived from the Gibbs energy and expressed in terms of model parameters.

Original languageEnglish (US)
Pages (from-to)2829-2837
Number of pages9
JournalChemical Engineering Science
Volume41
Issue number11
DOIs
StatePublished - 1986

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Fingerprint Dive into the research topics of 'Simplified chemical-physical theory for liquid metal solutions-I. Temperature dependence of the gibbs energy'. Together they form a unique fingerprint.

  • Cite this