Abstract
Photopolymerized composites are used in a broad range of applications with their performance largely directed by reaction kinetics and contraction accompanying polymerization. Herein, we demonstrate an instrument capable of simultaneously collecting multiple kinetics parameters for a wide range of photopolymerizable systems: degree of conversion (DC), reaction exotherm, and polymerization stress (PS). Our system consists of a cantilever beam-based instrument (tensometer) that has been optimized to capture a large range of stresses. The sample configuration allows the tensometer being coupled to a fast near infrared (NIR) spectrometer collecting spectra in transmission. Using our instrument design, simultaneous measurements of PS, DC, and exotherm are performed, for the first time, on a commercial composite with ~80 % (by mass) silica particle fillers. This new system is expected to provide new insights into kinetics and property relationships for photopolymerized composites.
Original language | English (US) |
---|---|
Title of host publication | Experimental and Applied Mechanics - Proceedings of the 2015 Annual Conference on Experimental and Applied Mechanics |
Editors | John Considine, Cesar Sciammarella, Paul Gloeckner |
Publisher | Springer New York LLC |
Pages | 149-153 |
Number of pages | 5 |
ISBN (Print) | 9783319224480 |
DOIs | |
State | Published - Jan 1 2016 |
Event | SEM Annual Conference and Exposition on Experimental and Applied Mechanics, 2015 - Costa Mesa, United States Duration: Jun 8 2015 → Jun 11 2015 |
Publication series
Name | Conference Proceedings of the Society for Experimental Mechanics Series |
---|---|
Volume | 4 |
ISSN (Print) | 2191-5644 |
ISSN (Electronic) | 2191-5652 |
Other
Other | SEM Annual Conference and Exposition on Experimental and Applied Mechanics, 2015 |
---|---|
Country | United States |
City | Costa Mesa |
Period | 6/8/15 → 6/11/15 |
Fingerprint
All Science Journal Classification (ASJC) codes
- Engineering(all)
- Computational Mechanics
- Mechanical Engineering
Cite this
}
Simultaneous measurement of polymerization stress evolution, conversion kinetics, and exotherm in real-time. / Wang, Zhengzhi; Landis, Forrest A.; Giuseppetti, Anthony A M; Lin-Gibson, Sheng; Chiang, Martin Y M.
Experimental and Applied Mechanics - Proceedings of the 2015 Annual Conference on Experimental and Applied Mechanics. ed. / John Considine; Cesar Sciammarella; Paul Gloeckner. Springer New York LLC, 2016. p. 149-153 (Conference Proceedings of the Society for Experimental Mechanics Series; Vol. 4).Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
TY - GEN
T1 - Simultaneous measurement of polymerization stress evolution, conversion kinetics, and exotherm in real-time
AU - Wang, Zhengzhi
AU - Landis, Forrest A.
AU - Giuseppetti, Anthony A M
AU - Lin-Gibson, Sheng
AU - Chiang, Martin Y M
PY - 2016/1/1
Y1 - 2016/1/1
N2 - Photopolymerized composites are used in a broad range of applications with their performance largely directed by reaction kinetics and contraction accompanying polymerization. Herein, we demonstrate an instrument capable of simultaneously collecting multiple kinetics parameters for a wide range of photopolymerizable systems: degree of conversion (DC), reaction exotherm, and polymerization stress (PS). Our system consists of a cantilever beam-based instrument (tensometer) that has been optimized to capture a large range of stresses. The sample configuration allows the tensometer being coupled to a fast near infrared (NIR) spectrometer collecting spectra in transmission. Using our instrument design, simultaneous measurements of PS, DC, and exotherm are performed, for the first time, on a commercial composite with ~80 % (by mass) silica particle fillers. This new system is expected to provide new insights into kinetics and property relationships for photopolymerized composites.
AB - Photopolymerized composites are used in a broad range of applications with their performance largely directed by reaction kinetics and contraction accompanying polymerization. Herein, we demonstrate an instrument capable of simultaneously collecting multiple kinetics parameters for a wide range of photopolymerizable systems: degree of conversion (DC), reaction exotherm, and polymerization stress (PS). Our system consists of a cantilever beam-based instrument (tensometer) that has been optimized to capture a large range of stresses. The sample configuration allows the tensometer being coupled to a fast near infrared (NIR) spectrometer collecting spectra in transmission. Using our instrument design, simultaneous measurements of PS, DC, and exotherm are performed, for the first time, on a commercial composite with ~80 % (by mass) silica particle fillers. This new system is expected to provide new insights into kinetics and property relationships for photopolymerized composites.
UR - http://www.scopus.com/inward/record.url?scp=84951995588&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84951995588&partnerID=8YFLogxK
U2 - 10.1007/978-3-319-22449-7_18
DO - 10.1007/978-3-319-22449-7_18
M3 - Conference contribution
AN - SCOPUS:84951995588
SN - 9783319224480
T3 - Conference Proceedings of the Society for Experimental Mechanics Series
SP - 149
EP - 153
BT - Experimental and Applied Mechanics - Proceedings of the 2015 Annual Conference on Experimental and Applied Mechanics
A2 - Considine, John
A2 - Sciammarella, Cesar
A2 - Gloeckner, Paul
PB - Springer New York LLC
ER -