Single-mode microwave sintering of Er:Al2O3

Robert Pavlacka, Claire Brennan, Victoria Blair, Raymond Brennan, Constantine Fountzoulas, Jiping Cheng, Dinesh Agrawal

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Scopus citations

Abstract

Er:Al2O3 powders were synthesized by co-precipitation and sintered using either traditional pressure-less sintering or microwave sintering. By utilizing two different types of microwave sintering, multi-mode and single-mode, the effect of different types of microwave fields on the sintering behavior of Er:Al2O3 was studied. Using single-mode microwave sintering, the percentages of electric and magnetic fields that the sample was exposed to during sintering was varied by adjusting the position of the sample along the processing microwave cavity. This experimental parameter has not been widely explored in microwave sintering, and may provide new insight into how the different fields affect a variety of processes throughout the sintering process. Our preliminary results suggest that this may be the case. Overall, the microwave sintering parameters appear to have a profound influence on the densification and, possibly, RE migration/phase stability. Sintering in the single-mode microwave system, with a 30%E:70%H mixed field produced samples with significantly higher density (∼97% of theoretical of alumina) than all of the other samples sintered at 1400°C (and equal to the sample conventionally sintered at 1700°C). This high density represents a significant improvement over the conventionally-sintered (1400°C) sample, which had a density ∼70% of the theoretical density. Whether due to the higher density or a microwave effect in itself, this sample also contained the least amount of second phase, which indicated that more Er formed a solid solution with Al2O3. While our results indicated mat densification and Er stability within the lattice may both improve with increasing magnetic field, our data is too limited to form a concrete conclusion. Regardless, our findings suggest that the magnetic component may play a critical, if not well understood, role in the processing of weakly magnetic materials such as Al2O3, and that the dopant material (RE in this case) may play an important role to the material response to the EM fields.

Original languageEnglish (US)
Title of host publicationProcessing and Properties of Advanced Ceramics and Composites VII
EditorsMorsi M. Mahmoud, Amar Bhalla, Narottam P. Bansal, J. P. Singh, Ricardo H. R. Castro, Navin Jose Manjooran, Gary Pickrell, Sylvia Johnson, Geoff Brennecka, Gurpreet Singh, Dongming Zhu
PublisherAmerican Ceramic Society
Pages3-11
Number of pages9
ISBN (Electronic)9781119183877
DOIs
StatePublished - 2015
EventProcessing and Properties of Advanced Ceramics and Composites VII - Materials Science and Technology 2014 Conference, MS and T 2014 - Pittsburgh, United States
Duration: Oct 12 2014Oct 16 2014

Publication series

NameCeramic Transactions
Volume252
ISSN (Print)1042-1122

Other

OtherProcessing and Properties of Advanced Ceramics and Composites VII - Materials Science and Technology 2014 Conference, MS and T 2014
CountryUnited States
CityPittsburgh
Period10/12/1410/16/14

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

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