Single-phase and Diphasic Aerogels and Xerogels of Mullite

Preparation and Characterization

Sridhar Komarneni, Claire Rutiser

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

Single-phase mullite composition gels have been synthesized using tetraethoxysilane [Si(OC2H5)4] and aluminum nitrate nonahydrate as precursors. Diphasic mullite gels have been prepared using colloidal silica and boehmite as precursors. Xerogels and aerogels of both the above gels have been obtained by ordinary drying in air at 60°C and critical point drying in methanol, respectively. Single-phase xerogels show an intense exothermic peak at about 980°C while their counterparts, aerogels, do not show any detectable exotherm by differential thermal analysis (DTA). These results suggest that the structure of single phase gels changed during critical point drying and the structural changes were investigated by solid-state 27Al magic angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy. No differences between diphasic xerogels and aerogels could be detected by DTA because there was little or no effect of drying on the discrete silica and alumina phases. The tetrahedral coordination of Al in single-phase mullite gel changed to octahedral coordination as detected by MAS NMR during critical point drying, which suggests that the alumina component segregated. Both single-phase and diphasic aerogels of mullite composition showed very high surface areas in the temperature range 1000-1400° C and these may be useful for high temperature catalytic applications.

Original languageEnglish (US)
Pages (from-to)143-147
Number of pages5
JournalJournal of the European Ceramic Society
Volume16
Issue number2 SPEC. ISS.
DOIs
StatePublished - Jan 1 1996

Fingerprint

Xerogels
Aerogels
Mullite
Drying
Gels
Magic angle spinning
Aluminum Oxide
Silicon Dioxide
Differential thermal analysis
Alumina
Silica
Chemical analysis
Nuclear magnetic resonance spectroscopy
Methanol
Nitrates
Nuclear magnetic resonance
aluminosilicate
Aluminum
Temperature
Polymers

All Science Journal Classification (ASJC) codes

  • Ceramics and Composites
  • Materials Chemistry

Cite this

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abstract = "Single-phase mullite composition gels have been synthesized using tetraethoxysilane [Si(OC2H5)4] and aluminum nitrate nonahydrate as precursors. Diphasic mullite gels have been prepared using colloidal silica and boehmite as precursors. Xerogels and aerogels of both the above gels have been obtained by ordinary drying in air at 60°C and critical point drying in methanol, respectively. Single-phase xerogels show an intense exothermic peak at about 980°C while their counterparts, aerogels, do not show any detectable exotherm by differential thermal analysis (DTA). These results suggest that the structure of single phase gels changed during critical point drying and the structural changes were investigated by solid-state 27Al magic angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy. No differences between diphasic xerogels and aerogels could be detected by DTA because there was little or no effect of drying on the discrete silica and alumina phases. The tetrahedral coordination of Al in single-phase mullite gel changed to octahedral coordination as detected by MAS NMR during critical point drying, which suggests that the alumina component segregated. Both single-phase and diphasic aerogels of mullite composition showed very high surface areas in the temperature range 1000-1400° C and these may be useful for high temperature catalytic applications.",
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Single-phase and Diphasic Aerogels and Xerogels of Mullite : Preparation and Characterization. / Komarneni, Sridhar; Rutiser, Claire.

In: Journal of the European Ceramic Society, Vol. 16, No. 2 SPEC. ISS., 01.01.1996, p. 143-147.

Research output: Contribution to journalArticle

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