Single Site Metal Ions on the Surface of TiO2 Nanorods - A Platform for Theoretical and Experimental Investigation

Saravanakumar T. Pillai, Tom Fischer, Tyler T. Clikeman, Jennifer Esbenshade, Catherine G P. Berdanier, Heather Rohwer, Mark Jastram, Wonjun Kang, Choumini Balasanthiran, Charles S. Spanjers, Talgat Inerbaev, Dmitri S. Kilin, Robert Martin Rioux, Jr., James D. Hoefelmeyer

Research output: Chapter in Book/Report/Conference proceedingChapter

2 Citations (Scopus)

Abstract

We demonstrate attachment of first-row transition metal ions to the surface of TiO2 nanorods. The metallated TiO2 nanorods were characterized with TEM, powder XRD, UV-visible, XAS, XPS, ICP-AES elemental analysis, and energy-dispersive X-ray spectroscopy. The materials can be readily studied using computational methods to provide valuable theoretical insight to the electron structure properties as well as charge-carrier dynamics. The materials are a testbed in which a feedback loop of computational and experimental results could guide the project toward the ultimate goal of creating optimized photocatalysts for solar energy utilization.

Original languageEnglish (US)
Title of host publicationPhotoinduced Processes at Surfaces and in Nanomaterials
EditorsDmitri Kilin
PublisherAmerican Chemical Society
Pages103-116
Number of pages14
ISBN (Electronic)9780841230941
DOIs
StatePublished - Jan 1 2015

Publication series

NameACS Symposium Series
Volume1196
ISSN (Print)0097-6156
ISSN (Electronic)1947-5918

Fingerprint

Nanorods
Metal ions
Photocatalysts
Computational methods
Testbeds
Charge carriers
Powders
Solar energy
Transition metals
Energy utilization
X ray photoelectron spectroscopy
Transmission electron microscopy
Feedback
Electrons
Chemical analysis
X-Ray Emission Spectrometry

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Pillai, S. T., Fischer, T., Clikeman, T. T., Esbenshade, J., Berdanier, C. G. P., Rohwer, H., ... Hoefelmeyer, J. D. (2015). Single Site Metal Ions on the Surface of TiO2 Nanorods - A Platform for Theoretical and Experimental Investigation. In D. Kilin (Ed.), Photoinduced Processes at Surfaces and in Nanomaterials (pp. 103-116). (ACS Symposium Series; Vol. 1196). American Chemical Society. https://doi.org/10.1021/bk-2015-1196.ch004
Pillai, Saravanakumar T. ; Fischer, Tom ; Clikeman, Tyler T. ; Esbenshade, Jennifer ; Berdanier, Catherine G P. ; Rohwer, Heather ; Jastram, Mark ; Kang, Wonjun ; Balasanthiran, Choumini ; Spanjers, Charles S. ; Inerbaev, Talgat ; Kilin, Dmitri S. ; Rioux, Jr., Robert Martin ; Hoefelmeyer, James D. / Single Site Metal Ions on the Surface of TiO2 Nanorods - A Platform for Theoretical and Experimental Investigation. Photoinduced Processes at Surfaces and in Nanomaterials. editor / Dmitri Kilin. American Chemical Society, 2015. pp. 103-116 (ACS Symposium Series).
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abstract = "We demonstrate attachment of first-row transition metal ions to the surface of TiO2 nanorods. The metallated TiO2 nanorods were characterized with TEM, powder XRD, UV-visible, XAS, XPS, ICP-AES elemental analysis, and energy-dispersive X-ray spectroscopy. The materials can be readily studied using computational methods to provide valuable theoretical insight to the electron structure properties as well as charge-carrier dynamics. The materials are a testbed in which a feedback loop of computational and experimental results could guide the project toward the ultimate goal of creating optimized photocatalysts for solar energy utilization.",
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Pillai, ST, Fischer, T, Clikeman, TT, Esbenshade, J, Berdanier, CGP, Rohwer, H, Jastram, M, Kang, W, Balasanthiran, C, Spanjers, CS, Inerbaev, T, Kilin, DS, Rioux, Jr., RM & Hoefelmeyer, JD 2015, Single Site Metal Ions on the Surface of TiO2 Nanorods - A Platform for Theoretical and Experimental Investigation. in D Kilin (ed.), Photoinduced Processes at Surfaces and in Nanomaterials. ACS Symposium Series, vol. 1196, American Chemical Society, pp. 103-116. https://doi.org/10.1021/bk-2015-1196.ch004

Single Site Metal Ions on the Surface of TiO2 Nanorods - A Platform for Theoretical and Experimental Investigation. / Pillai, Saravanakumar T.; Fischer, Tom; Clikeman, Tyler T.; Esbenshade, Jennifer; Berdanier, Catherine G P.; Rohwer, Heather; Jastram, Mark; Kang, Wonjun; Balasanthiran, Choumini; Spanjers, Charles S.; Inerbaev, Talgat; Kilin, Dmitri S.; Rioux, Jr., Robert Martin; Hoefelmeyer, James D.

Photoinduced Processes at Surfaces and in Nanomaterials. ed. / Dmitri Kilin. American Chemical Society, 2015. p. 103-116 (ACS Symposium Series; Vol. 1196).

Research output: Chapter in Book/Report/Conference proceedingChapter

TY - CHAP

T1 - Single Site Metal Ions on the Surface of TiO2 Nanorods - A Platform for Theoretical and Experimental Investigation

AU - Pillai, Saravanakumar T.

AU - Fischer, Tom

AU - Clikeman, Tyler T.

AU - Esbenshade, Jennifer

AU - Berdanier, Catherine G P.

AU - Rohwer, Heather

AU - Jastram, Mark

AU - Kang, Wonjun

AU - Balasanthiran, Choumini

AU - Spanjers, Charles S.

AU - Inerbaev, Talgat

AU - Kilin, Dmitri S.

AU - Rioux, Jr., Robert Martin

AU - Hoefelmeyer, James D.

PY - 2015/1/1

Y1 - 2015/1/1

N2 - We demonstrate attachment of first-row transition metal ions to the surface of TiO2 nanorods. The metallated TiO2 nanorods were characterized with TEM, powder XRD, UV-visible, XAS, XPS, ICP-AES elemental analysis, and energy-dispersive X-ray spectroscopy. The materials can be readily studied using computational methods to provide valuable theoretical insight to the electron structure properties as well as charge-carrier dynamics. The materials are a testbed in which a feedback loop of computational and experimental results could guide the project toward the ultimate goal of creating optimized photocatalysts for solar energy utilization.

AB - We demonstrate attachment of first-row transition metal ions to the surface of TiO2 nanorods. The metallated TiO2 nanorods were characterized with TEM, powder XRD, UV-visible, XAS, XPS, ICP-AES elemental analysis, and energy-dispersive X-ray spectroscopy. The materials can be readily studied using computational methods to provide valuable theoretical insight to the electron structure properties as well as charge-carrier dynamics. The materials are a testbed in which a feedback loop of computational and experimental results could guide the project toward the ultimate goal of creating optimized photocatalysts for solar energy utilization.

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M3 - Chapter

T3 - ACS Symposium Series

SP - 103

EP - 116

BT - Photoinduced Processes at Surfaces and in Nanomaterials

A2 - Kilin, Dmitri

PB - American Chemical Society

ER -

Pillai ST, Fischer T, Clikeman TT, Esbenshade J, Berdanier CGP, Rohwer H et al. Single Site Metal Ions on the Surface of TiO2 Nanorods - A Platform for Theoretical and Experimental Investigation. In Kilin D, editor, Photoinduced Processes at Surfaces and in Nanomaterials. American Chemical Society. 2015. p. 103-116. (ACS Symposium Series). https://doi.org/10.1021/bk-2015-1196.ch004