Soft chemistry of ion-exchangeable layered metal oxides

Ritesh Uppuluri, Arnab Sen Gupta, Alyssa S. Rosas, Thomas E. Mallouk

Research output: Contribution to journalReview article

20 Citations (Scopus)

Abstract

Soft chemical reactions such as ion-exchange and acid-base reactions have been extensively investigated to synthesize novel metastable layered inorganic solids, to exfoliate them into individual nanosheets, and to re-assemble them as thin films and nanocomposite materials. These reactions proceed at relatively low temperature and enable the synthesis of a rich variety of structures by stepwise reactions. In recent years, the toolbox of soft chemical reactions has been utilized to rationally design and tailor the properties of functional layered transition metal oxides. Layer-by-layer assembly and intercalation chemistry have provided insight into covalent interactions that stabilize oxide-supported nanoparticle catalysts. In addition, topochemical reactions have been utilized to tune the compositions of layered perovskite oxides in order to break inversion symmetry, resulting in piezoelectric and ferroelectric properties. This review focuses on the use of soft chemical approaches to design functional layered transition metal oxides with tunable properties. Soft chemical reactions enable the design of functional materials for diverse applications that include artificial photosynthesis, catalysis, energy storage, fuel cells, optical sensors, ferroics, and high-k dielectrics.

Original languageEnglish (US)
Pages (from-to)2401-2430
Number of pages30
JournalChemical Society Reviews
Volume47
Issue number7
DOIs
StatePublished - Apr 7 2018

Fingerprint

Oxides
Metals
Ions
Chemical reactions
Transition metals
Addition reactions
Functional materials
Photosynthesis
Nanosheets
Optical sensors
Intercalation
Energy storage
Catalysis
Ferroelectric materials
Fuel cells
Ion exchange
Nanocomposites
Nanoparticles
Thin films
Catalysts

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Uppuluri, R., Sen Gupta, A., Rosas, A. S., & Mallouk, T. E. (2018). Soft chemistry of ion-exchangeable layered metal oxides. Chemical Society Reviews, 47(7), 2401-2430. https://doi.org/10.1039/c7cs00290d
Uppuluri, Ritesh ; Sen Gupta, Arnab ; Rosas, Alyssa S. ; Mallouk, Thomas E. / Soft chemistry of ion-exchangeable layered metal oxides. In: Chemical Society Reviews. 2018 ; Vol. 47, No. 7. pp. 2401-2430.
@article{08ff3b0854aa44a6ba384be01bb9a857,
title = "Soft chemistry of ion-exchangeable layered metal oxides",
abstract = "Soft chemical reactions such as ion-exchange and acid-base reactions have been extensively investigated to synthesize novel metastable layered inorganic solids, to exfoliate them into individual nanosheets, and to re-assemble them as thin films and nanocomposite materials. These reactions proceed at relatively low temperature and enable the synthesis of a rich variety of structures by stepwise reactions. In recent years, the toolbox of soft chemical reactions has been utilized to rationally design and tailor the properties of functional layered transition metal oxides. Layer-by-layer assembly and intercalation chemistry have provided insight into covalent interactions that stabilize oxide-supported nanoparticle catalysts. In addition, topochemical reactions have been utilized to tune the compositions of layered perovskite oxides in order to break inversion symmetry, resulting in piezoelectric and ferroelectric properties. This review focuses on the use of soft chemical approaches to design functional layered transition metal oxides with tunable properties. Soft chemical reactions enable the design of functional materials for diverse applications that include artificial photosynthesis, catalysis, energy storage, fuel cells, optical sensors, ferroics, and high-k dielectrics.",
author = "Ritesh Uppuluri and {Sen Gupta}, Arnab and Rosas, {Alyssa S.} and Mallouk, {Thomas E.}",
year = "2018",
month = "4",
day = "7",
doi = "10.1039/c7cs00290d",
language = "English (US)",
volume = "47",
pages = "2401--2430",
journal = "Chemical Society Reviews",
issn = "0306-0012",
publisher = "Royal Society of Chemistry",
number = "7",

}

Uppuluri, R, Sen Gupta, A, Rosas, AS & Mallouk, TE 2018, 'Soft chemistry of ion-exchangeable layered metal oxides', Chemical Society Reviews, vol. 47, no. 7, pp. 2401-2430. https://doi.org/10.1039/c7cs00290d

Soft chemistry of ion-exchangeable layered metal oxides. / Uppuluri, Ritesh; Sen Gupta, Arnab; Rosas, Alyssa S.; Mallouk, Thomas E.

In: Chemical Society Reviews, Vol. 47, No. 7, 07.04.2018, p. 2401-2430.

Research output: Contribution to journalReview article

TY - JOUR

T1 - Soft chemistry of ion-exchangeable layered metal oxides

AU - Uppuluri, Ritesh

AU - Sen Gupta, Arnab

AU - Rosas, Alyssa S.

AU - Mallouk, Thomas E.

PY - 2018/4/7

Y1 - 2018/4/7

N2 - Soft chemical reactions such as ion-exchange and acid-base reactions have been extensively investigated to synthesize novel metastable layered inorganic solids, to exfoliate them into individual nanosheets, and to re-assemble them as thin films and nanocomposite materials. These reactions proceed at relatively low temperature and enable the synthesis of a rich variety of structures by stepwise reactions. In recent years, the toolbox of soft chemical reactions has been utilized to rationally design and tailor the properties of functional layered transition metal oxides. Layer-by-layer assembly and intercalation chemistry have provided insight into covalent interactions that stabilize oxide-supported nanoparticle catalysts. In addition, topochemical reactions have been utilized to tune the compositions of layered perovskite oxides in order to break inversion symmetry, resulting in piezoelectric and ferroelectric properties. This review focuses on the use of soft chemical approaches to design functional layered transition metal oxides with tunable properties. Soft chemical reactions enable the design of functional materials for diverse applications that include artificial photosynthesis, catalysis, energy storage, fuel cells, optical sensors, ferroics, and high-k dielectrics.

AB - Soft chemical reactions such as ion-exchange and acid-base reactions have been extensively investigated to synthesize novel metastable layered inorganic solids, to exfoliate them into individual nanosheets, and to re-assemble them as thin films and nanocomposite materials. These reactions proceed at relatively low temperature and enable the synthesis of a rich variety of structures by stepwise reactions. In recent years, the toolbox of soft chemical reactions has been utilized to rationally design and tailor the properties of functional layered transition metal oxides. Layer-by-layer assembly and intercalation chemistry have provided insight into covalent interactions that stabilize oxide-supported nanoparticle catalysts. In addition, topochemical reactions have been utilized to tune the compositions of layered perovskite oxides in order to break inversion symmetry, resulting in piezoelectric and ferroelectric properties. This review focuses on the use of soft chemical approaches to design functional layered transition metal oxides with tunable properties. Soft chemical reactions enable the design of functional materials for diverse applications that include artificial photosynthesis, catalysis, energy storage, fuel cells, optical sensors, ferroics, and high-k dielectrics.

UR - http://www.scopus.com/inward/record.url?scp=85044936045&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85044936045&partnerID=8YFLogxK

U2 - 10.1039/c7cs00290d

DO - 10.1039/c7cs00290d

M3 - Review article

C2 - 29479626

AN - SCOPUS:85044936045

VL - 47

SP - 2401

EP - 2430

JO - Chemical Society Reviews

JF - Chemical Society Reviews

SN - 0306-0012

IS - 7

ER -

Uppuluri R, Sen Gupta A, Rosas AS, Mallouk TE. Soft chemistry of ion-exchangeable layered metal oxides. Chemical Society Reviews. 2018 Apr 7;47(7):2401-2430. https://doi.org/10.1039/c7cs00290d