Soot nanostructure: Definition, quantification and implications

Research output: Contribution to conferencePaper

34 Citations (Scopus)

Abstract

Although the relation between carbon structure and reactivity is well-known from thermal and oxidative studies of coal, char and graphite, the relation for soot remains unstudied. In this article, the dependence of the soot oxidation rate upon nanostructure, namely the length, separation distance and curvature of the graphene segments is shown. Soots possessing graphitic, fullerenic or amorphous nanostructure are used for this comparison. Surprisingly, the different soot nanostructures are readily produced by using different fuels and pyrolysis conditions. Reflecting different ratios of edge to basal plane sites or amounts of ring strain imposed by curvature, burnout rates are found to differ by nearly 500% for the soots studied here. Using high resolution transmission electron images as input data, this paper interprets the varied oxidation rates in terms of differences in nanostructure between the soots. In addition to fringe length, the fringe analysis algorithm can also provide fringe separation distance and tortuosity. Results are shown in the form of histograms for each of these quantities. The combination of the three measurements can give a better indication of the graphitic structure within nanoscale carbons and can distinguish carbon nanostructure based upon fullerenic, graphitic and amorphous content.

Original languageEnglish (US)
DOIs
StatePublished - Dec 1 2005
Event2005 SAE World Congress - Detroit, MI, United States
Duration: Apr 11 2005Apr 14 2005

Other

Other2005 SAE World Congress
CountryUnited States
CityDetroit, MI
Period4/11/054/14/05

Fingerprint

Soot
Nanostructures
Carbon
Oxidation
Graphene
Graphite
Pyrolysis
Coal
Electrons

All Science Journal Classification (ASJC) codes

  • Automotive Engineering
  • Safety, Risk, Reliability and Quality
  • Pollution
  • Industrial and Manufacturing Engineering

Cite this

Vander Wal, R. L. (2005). Soot nanostructure: Definition, quantification and implications. Paper presented at 2005 SAE World Congress, Detroit, MI, United States. https://doi.org/10.4271/2005-01-0964
Vander Wal, Randy Lee. / Soot nanostructure : Definition, quantification and implications. Paper presented at 2005 SAE World Congress, Detroit, MI, United States.
@conference{890ed4a9fe4e4ee99205b12e39a349b6,
title = "Soot nanostructure: Definition, quantification and implications",
abstract = "Although the relation between carbon structure and reactivity is well-known from thermal and oxidative studies of coal, char and graphite, the relation for soot remains unstudied. In this article, the dependence of the soot oxidation rate upon nanostructure, namely the length, separation distance and curvature of the graphene segments is shown. Soots possessing graphitic, fullerenic or amorphous nanostructure are used for this comparison. Surprisingly, the different soot nanostructures are readily produced by using different fuels and pyrolysis conditions. Reflecting different ratios of edge to basal plane sites or amounts of ring strain imposed by curvature, burnout rates are found to differ by nearly 500{\%} for the soots studied here. Using high resolution transmission electron images as input data, this paper interprets the varied oxidation rates in terms of differences in nanostructure between the soots. In addition to fringe length, the fringe analysis algorithm can also provide fringe separation distance and tortuosity. Results are shown in the form of histograms for each of these quantities. The combination of the three measurements can give a better indication of the graphitic structure within nanoscale carbons and can distinguish carbon nanostructure based upon fullerenic, graphitic and amorphous content.",
author = "{Vander Wal}, {Randy Lee}",
year = "2005",
month = "12",
day = "1",
doi = "10.4271/2005-01-0964",
language = "English (US)",
note = "2005 SAE World Congress ; Conference date: 11-04-2005 Through 14-04-2005",

}

Vander Wal, RL 2005, 'Soot nanostructure: Definition, quantification and implications', Paper presented at 2005 SAE World Congress, Detroit, MI, United States, 4/11/05 - 4/14/05. https://doi.org/10.4271/2005-01-0964

Soot nanostructure : Definition, quantification and implications. / Vander Wal, Randy Lee.

2005. Paper presented at 2005 SAE World Congress, Detroit, MI, United States.

Research output: Contribution to conferencePaper

TY - CONF

T1 - Soot nanostructure

T2 - Definition, quantification and implications

AU - Vander Wal, Randy Lee

PY - 2005/12/1

Y1 - 2005/12/1

N2 - Although the relation between carbon structure and reactivity is well-known from thermal and oxidative studies of coal, char and graphite, the relation for soot remains unstudied. In this article, the dependence of the soot oxidation rate upon nanostructure, namely the length, separation distance and curvature of the graphene segments is shown. Soots possessing graphitic, fullerenic or amorphous nanostructure are used for this comparison. Surprisingly, the different soot nanostructures are readily produced by using different fuels and pyrolysis conditions. Reflecting different ratios of edge to basal plane sites or amounts of ring strain imposed by curvature, burnout rates are found to differ by nearly 500% for the soots studied here. Using high resolution transmission electron images as input data, this paper interprets the varied oxidation rates in terms of differences in nanostructure between the soots. In addition to fringe length, the fringe analysis algorithm can also provide fringe separation distance and tortuosity. Results are shown in the form of histograms for each of these quantities. The combination of the three measurements can give a better indication of the graphitic structure within nanoscale carbons and can distinguish carbon nanostructure based upon fullerenic, graphitic and amorphous content.

AB - Although the relation between carbon structure and reactivity is well-known from thermal and oxidative studies of coal, char and graphite, the relation for soot remains unstudied. In this article, the dependence of the soot oxidation rate upon nanostructure, namely the length, separation distance and curvature of the graphene segments is shown. Soots possessing graphitic, fullerenic or amorphous nanostructure are used for this comparison. Surprisingly, the different soot nanostructures are readily produced by using different fuels and pyrolysis conditions. Reflecting different ratios of edge to basal plane sites or amounts of ring strain imposed by curvature, burnout rates are found to differ by nearly 500% for the soots studied here. Using high resolution transmission electron images as input data, this paper interprets the varied oxidation rates in terms of differences in nanostructure between the soots. In addition to fringe length, the fringe analysis algorithm can also provide fringe separation distance and tortuosity. Results are shown in the form of histograms for each of these quantities. The combination of the three measurements can give a better indication of the graphitic structure within nanoscale carbons and can distinguish carbon nanostructure based upon fullerenic, graphitic and amorphous content.

UR - http://www.scopus.com/inward/record.url?scp=84867640664&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84867640664&partnerID=8YFLogxK

U2 - 10.4271/2005-01-0964

DO - 10.4271/2005-01-0964

M3 - Paper

ER -

Vander Wal RL. Soot nanostructure: Definition, quantification and implications. 2005. Paper presented at 2005 SAE World Congress, Detroit, MI, United States. https://doi.org/10.4271/2005-01-0964