Spectroelectrochemical measurements of second-order catalytic reaction rates using signal averaging

Henry N. Blount, Nicholas Winograd, Theodore Kuwana

Research output: Contribution to journalArticle

52 Scopus citations

Abstract

The technique of digital simulation has been applied to the spectroelectrochemical evaluation of the kinetics of second-order catalytic reactions following charge transfer. The validity of this approach has been demonstrated using a previously reported system, electrogenerated ferricyanide in the presence of ascorbic acid. Also the kinetics of the tri-p-anisylamine radical cation-cyanide catalytic system have been measured under second-order conditions employing signal averaging techniques for double potential step and open circuit relaxation experiments, and these results are in agreement with internal reflection spectroscopic measurements obtained under pseudo-first-order conditions.

Original languageEnglish (US)
Pages (from-to)3231-3236
Number of pages6
JournalJournal of physical chemistry
Volume74
Issue number17
DOIs
StatePublished - Jan 1 1970

All Science Journal Classification (ASJC) codes

  • Engineering(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Spectroelectrochemical measurements of second-order catalytic reaction rates using signal averaging'. Together they form a unique fingerprint.

  • Cite this