Spectroscopy, persistent hole burning, and holographic applications of naphtophthalocyanine/haloanthracene systems

R. S. Pandher, A. A. Gorokhovsky, Z. Liu, I. V. Solomatin, Demetri Psaltis

Research output: Contribution to journalConference articlepeer-review

2 Scopus citations

Abstract

We report on the spectroscopic and hole burning properties of free-base naphtophthalocyanine with and without 1-chloranthracene in polymer host. These materials exhibit a strong 0-0 absorption band in the region 800 nm matching the wavelength range of most semiconductor and Ti:Sapphire lasers. The materials studied feature two persistent hole burning photochemical mechanisms, i.e. one-photon proton tautomerization, and two-photon-gated hole burning likely due to donor-acceptor electron transfer. The last mechanism includes the long living intermediate state. The hole width at 1.5 K is about 300-400 MHz depending on the hole burning conditions, while the inhomogeneous width is about 107 MHz. Holographic storage is an important potential application of these materials. We demonstrated 10 plane wave holograms angularly multiplexed at one frequency channel in a spectral hole burning medium. It was shown that the M/# is still a valid system metric and the measured M/# in one frequency channel is about 0.01.

Original languageEnglish (US)
Pages (from-to)207-212
Number of pages6
JournalJournal of Luminescence
Volume98
Issue number1-4
DOIs
StatePublished - Jul 2002
EventHBSM 2001 - Taipei, Taiwan, Province of China
Duration: Nov 18 2001Nov 23 2001

All Science Journal Classification (ASJC) codes

  • Biophysics
  • Biochemistry
  • Chemistry(all)
  • Atomic and Molecular Physics, and Optics
  • Condensed Matter Physics

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