Sputtering yields for C60 and Au3 bombardment of water ice as a function of incident kinetic energy

Michael F. Russo, Christopher Szakal, Joseph Kozole, Nicholas Winograd, Barbara Jane Garrison

Research output: Contribution to journalArticle

57 Citations (Scopus)

Abstract

The total sputtering yields for water ice due to kiloelectronvolt cluster bombardment have been measured and compared to the predictions made by the mesoscale energy deposition footprint (MEDF) model. For C60 bombardment, the experimental yield varies almost linearly from 820 water molecule equivalents at an incident kinetic energy of 10 keV to 10 100 water molecule equivalents at a kinetic energy of 120 keV. For Au3 bombardment, the experimental yield varies almost linearly from 630 water molecule equivalents at an incident energy of 10 keV and rises to 1200 water molecule equivalents at 25 keV. The MEDF model is used to calculate relative yield trends with respect to incident energy using short-time molecular dynamics simulations. The results of these calculations indicate that the model can effectively predict the yield trends observed for these two clusters in experiments, although there is a consistent overestimate of the predicted induced C60 yield. It is hypothesized that this overestimate can be explained by the absence of reactions and ionization processes in the current simulations. Despite this omission, experimental yield trends can be accurately predicted using relatively small amounts of computer time. The success of the model in predicting the yield of water from ice films using a variety of energies and projectiles suggests this approach may greatly aid in the optimization of experimental configurations.

Original languageEnglish (US)
Pages (from-to)4493-4498
Number of pages6
JournalAnalytical Chemistry
Volume79
Issue number12
DOIs
StatePublished - Jun 15 2007

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Ice
Kinetic energy
Sputtering
Water
Molecules
Projectiles
Ionization
Molecular dynamics
Computer simulation
Experiments

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry

Cite this

Russo, Michael F. ; Szakal, Christopher ; Kozole, Joseph ; Winograd, Nicholas ; Garrison, Barbara Jane. / Sputtering yields for C60 and Au3 bombardment of water ice as a function of incident kinetic energy. In: Analytical Chemistry. 2007 ; Vol. 79, No. 12. pp. 4493-4498.
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Sputtering yields for C60 and Au3 bombardment of water ice as a function of incident kinetic energy. / Russo, Michael F.; Szakal, Christopher; Kozole, Joseph; Winograd, Nicholas; Garrison, Barbara Jane.

In: Analytical Chemistry, Vol. 79, No. 12, 15.06.2007, p. 4493-4498.

Research output: Contribution to journalArticle

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