Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; Preparation and redox behavior

Dennis Awasabisah, Nan Xu, Krishna P. Sharmah Gautam, Douglas R. Powell, Michael J. Shaw, George B. Richter-Addo

Research output: Contribution to journalArticle

7 Scopus citations

Abstract

The six-coordinate compounds, (T(p-OMe)PP)Ru(NO)(OC6HF 4) and (T(p-OMe)PP)Ru(NO)(OC(O)CF3) have been prepared and characterized by IR and NMR spectroscopy, electrochemistry and IR spectroelectrochemistry, and by X-ray crystallography. These compounds undergo macrocycle-centered oxidations, and loss of axial ligands upon reduction.

Original languageEnglish (US)
Pages (from-to)8537-8540
Number of pages4
JournalDalton Transactions
Volume42
Issue number24
DOIs
StatePublished - Jun 28 2013

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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    Awasabisah, D., Xu, N., Sharmah Gautam, K. P., Powell, D. R., Shaw, M. J., & Richter-Addo, G. B. (2013). Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; Preparation and redox behavior. Dalton Transactions, 42(24), 8537-8540. https://doi.org/10.1039/c3dt33109a