Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; Preparation and redox behavior

Dennis Awasabisah, Nan Xu, Krishna P. Sharmah Gautam, Douglas R. Powell, Michael J. Shaw, George B. Richter-Addo

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The six-coordinate compounds, (T(p-OMe)PP)Ru(NO)(OC6HF 4) and (T(p-OMe)PP)Ru(NO)(OC(O)CF3) have been prepared and characterized by IR and NMR spectroscopy, electrochemistry and IR spectroelectrochemistry, and by X-ray crystallography. These compounds undergo macrocycle-centered oxidations, and loss of axial ligands upon reduction.

Original languageEnglish (US)
Pages (from-to)8537-8540
Number of pages4
JournalDalton Transactions
Volume42
Issue number24
DOIs
StatePublished - Jun 28 2013

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Macrocyclic Compounds
Spectroelectrochemistry
Ruthenium
X ray crystallography
Porphyrins
Electrochemistry
Nuclear magnetic resonance spectroscopy
Infrared spectroscopy
Ligands
Oxidation
Oxidation-Reduction

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Awasabisah, D., Xu, N., Sharmah Gautam, K. P., Powell, D. R., Shaw, M. J., & Richter-Addo, G. B. (2013). Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; Preparation and redox behavior. Dalton Transactions, 42(24), 8537-8540. https://doi.org/10.1039/c3dt33109a
Awasabisah, Dennis ; Xu, Nan ; Sharmah Gautam, Krishna P. ; Powell, Douglas R. ; Shaw, Michael J. ; Richter-Addo, George B. / Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; Preparation and redox behavior. In: Dalton Transactions. 2013 ; Vol. 42, No. 24. pp. 8537-8540.
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Awasabisah, D, Xu, N, Sharmah Gautam, KP, Powell, DR, Shaw, MJ & Richter-Addo, GB 2013, 'Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; Preparation and redox behavior', Dalton Transactions, vol. 42, no. 24, pp. 8537-8540. https://doi.org/10.1039/c3dt33109a

Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; Preparation and redox behavior. / Awasabisah, Dennis; Xu, Nan; Sharmah Gautam, Krishna P.; Powell, Douglas R.; Shaw, Michael J.; Richter-Addo, George B.

In: Dalton Transactions, Vol. 42, No. 24, 28.06.2013, p. 8537-8540.

Research output: Contribution to journalArticle

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AU - Shaw, Michael J.

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Awasabisah D, Xu N, Sharmah Gautam KP, Powell DR, Shaw MJ, Richter-Addo GB. Stable ruthenium nitrosyl porphyrins with axial O-bonded ligands; Preparation and redox behavior. Dalton Transactions. 2013 Jun 28;42(24):8537-8540. https://doi.org/10.1039/c3dt33109a