Stereoselective Construction of the Complete Ingenane Ring System

Raymond Lee Funk, Thomas A. Olmstead, M. Parvez, John B. Stallman

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Abstract

A stereoselective route to the fully assembled and optically pure tetracyclic ring system of ingenol which features a macrocyclic Claisen rearrangement for the construction of the strained in,out-bridged bicyclic substructure and simultaneous, strategic placement of functionality has been developed.

Original languageEnglish (US)
Pages (from-to)5873-5875
Number of pages3
JournalJournal of Organic Chemistry
Volume58
Issue number22
DOIs
Publication statusPublished - Jan 1 1993

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All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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