TY - JOUR
T1 - Stick and slip behaviour of confined oligomer melts under shear. A molecular-dynamics study
AU - Manias, E.
AU - Hadziioannou, G.
AU - Bitsanis, I.
AU - Brinke, G. Ten
PY - 1993/10/10
Y1 - 1993/10/10
N2 - The flow behaviour of melts of short chains, confined in molecularly thin Couette flow geometries, is studied with molecular-dynamics simulations. The effect of wall attraction and confinement on the density and velocity profiles is analysed. In these highly inhomogeneous films, a strong correlation between the density and velocity profile is found. Sticking of the interfadal layer on the wall and slip on the wall and inside the film is manifested by changes in the velocity profile. The location of the slip is determined by the strength of the wall attraction.
AB - The flow behaviour of melts of short chains, confined in molecularly thin Couette flow geometries, is studied with molecular-dynamics simulations. The effect of wall attraction and confinement on the density and velocity profiles is analysed. In these highly inhomogeneous films, a strong correlation between the density and velocity profile is found. Sticking of the interfadal layer on the wall and slip on the wall and inside the film is manifested by changes in the velocity profile. The location of the slip is determined by the strength of the wall attraction.
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U2 - 10.1209/0295-5075/24/2/004
DO - 10.1209/0295-5075/24/2/004
M3 - Article
AN - SCOPUS:70349942189
VL - 24
SP - 99
EP - 104
JO - Journal de Physique (Paris), Lettres
JF - Journal de Physique (Paris), Lettres
SN - 0295-5075
IS - 2
ER -