Structural, conformational, and polarization changes of poly(vinylidene fluoride-trifluoroethylene) copolymer induced by high-energy electron irradiation

Haisheng Xu, G. Shanthi, V. Bharti, Q. M. Zhang, T. Ramotowski

    Research output: Contribution to journalArticle

    65 Citations (Scopus)

    Abstract

    Structural and molecular conformation changes of high-energy electron-irradiated poly(vinylidene fluoride-trifluoroethylene) 50/50 copolymer have been investigated by means of FT-IR spectroscopy, X-ray diffraction, and cross-linking density measurement and are compared with the change of polarization hysteresis loops with dose. Although in general the irradiation reduces the macroscopic polar ordering, which leads to the eventual disappearance of the remanent polarization in the copolymer at room temperature, the change in the mesoscopic structure and molecular conformation with dose is not monotonic. In the intermediate dose range, there is a reversal of the change of local ordering with dose, as revealed by the decrease of the fraction of the TG conformation in the copolymer and contraction of the lattice in directions perpendicular to the polymer chain with dose, which could be caused by the high cross-linking density due to irradiation. In addition, for irradiated polymers at doses above 30 Mrad, no transition behavior with temperature is observed in the FT-IR spectra, consistent with the early experimental results that the ferroelectric-paraelectric transition has been eliminated by irradiation.

    Original languageEnglish (US)
    Pages (from-to)4125-4131
    Number of pages7
    JournalMacromolecules
    Volume33
    Issue number11
    DOIs
    StatePublished - May 30 2000

    Fingerprint

    Electron irradiation
    Conformations
    Copolymers
    Irradiation
    Polarization
    Dosimetry
    Polymers
    Remanence
    Hysteresis loops
    Ferroelectric materials
    Infrared spectroscopy
    X ray diffraction
    Temperature
    Electrons
    vinylidene fluoride-trifluoroethylene copolymer
    polyvinylidene fluoride

    All Science Journal Classification (ASJC) codes

    • Organic Chemistry
    • Polymers and Plastics
    • Inorganic Chemistry
    • Materials Chemistry

    Cite this

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    title = "Structural, conformational, and polarization changes of poly(vinylidene fluoride-trifluoroethylene) copolymer induced by high-energy electron irradiation",
    abstract = "Structural and molecular conformation changes of high-energy electron-irradiated poly(vinylidene fluoride-trifluoroethylene) 50/50 copolymer have been investigated by means of FT-IR spectroscopy, X-ray diffraction, and cross-linking density measurement and are compared with the change of polarization hysteresis loops with dose. Although in general the irradiation reduces the macroscopic polar ordering, which leads to the eventual disappearance of the remanent polarization in the copolymer at room temperature, the change in the mesoscopic structure and molecular conformation with dose is not monotonic. In the intermediate dose range, there is a reversal of the change of local ordering with dose, as revealed by the decrease of the fraction of the TG conformation in the copolymer and contraction of the lattice in directions perpendicular to the polymer chain with dose, which could be caused by the high cross-linking density due to irradiation. In addition, for irradiated polymers at doses above 30 Mrad, no transition behavior with temperature is observed in the FT-IR spectra, consistent with the early experimental results that the ferroelectric-paraelectric transition has been eliminated by irradiation.",
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    Structural, conformational, and polarization changes of poly(vinylidene fluoride-trifluoroethylene) copolymer induced by high-energy electron irradiation. / Xu, Haisheng; Shanthi, G.; Bharti, V.; Zhang, Q. M.; Ramotowski, T.

    In: Macromolecules, Vol. 33, No. 11, 30.05.2000, p. 4125-4131.

    Research output: Contribution to journalArticle

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    AU - Xu, Haisheng

    AU - Shanthi, G.

    AU - Bharti, V.

    AU - Zhang, Q. M.

    AU - Ramotowski, T.

    PY - 2000/5/30

    Y1 - 2000/5/30

    N2 - Structural and molecular conformation changes of high-energy electron-irradiated poly(vinylidene fluoride-trifluoroethylene) 50/50 copolymer have been investigated by means of FT-IR spectroscopy, X-ray diffraction, and cross-linking density measurement and are compared with the change of polarization hysteresis loops with dose. Although in general the irradiation reduces the macroscopic polar ordering, which leads to the eventual disappearance of the remanent polarization in the copolymer at room temperature, the change in the mesoscopic structure and molecular conformation with dose is not monotonic. In the intermediate dose range, there is a reversal of the change of local ordering with dose, as revealed by the decrease of the fraction of the TG conformation in the copolymer and contraction of the lattice in directions perpendicular to the polymer chain with dose, which could be caused by the high cross-linking density due to irradiation. In addition, for irradiated polymers at doses above 30 Mrad, no transition behavior with temperature is observed in the FT-IR spectra, consistent with the early experimental results that the ferroelectric-paraelectric transition has been eliminated by irradiation.

    AB - Structural and molecular conformation changes of high-energy electron-irradiated poly(vinylidene fluoride-trifluoroethylene) 50/50 copolymer have been investigated by means of FT-IR spectroscopy, X-ray diffraction, and cross-linking density measurement and are compared with the change of polarization hysteresis loops with dose. Although in general the irradiation reduces the macroscopic polar ordering, which leads to the eventual disappearance of the remanent polarization in the copolymer at room temperature, the change in the mesoscopic structure and molecular conformation with dose is not monotonic. In the intermediate dose range, there is a reversal of the change of local ordering with dose, as revealed by the decrease of the fraction of the TG conformation in the copolymer and contraction of the lattice in directions perpendicular to the polymer chain with dose, which could be caused by the high cross-linking density due to irradiation. In addition, for irradiated polymers at doses above 30 Mrad, no transition behavior with temperature is observed in the FT-IR spectra, consistent with the early experimental results that the ferroelectric-paraelectric transition has been eliminated by irradiation.

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