Study of the products of the reactions of N2(A3Σu+): The effect of vibrational energy in N2(A)

Michael F. Golde, Alfred M. Moyle

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Abstract

The reactions of electronically excited N2(A3Σu+) molecules with selected small molecules have been studied in a discharge-flow system. A method is described for probing, with high sensitivity, the dependence of total quenching rate constants and reaction pathways on vibrational energy in the N2(A) state. Highly characteristic behavior is observed in the reactions with NH3, CH3OH, NO and O2.

Original languageEnglish (US)
Pages (from-to)375-380
Number of pages6
JournalChemical Physics Letters
Volume117
Issue number4
DOIs
StatePublished - Jun 21 1985

All Science Journal Classification (ASJC) codes

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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