Substituted 5-Phenyl-10, ll-DihydroDibenzo[b, f]Silepins and Reactions at the 10, II-Positions

Harry R. Allcock, T. A. Nugent, L. A. Smeltz

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The reaction between silicon tetrachloride and catechol in acetonitrile at 0° results in the formation of o-phenylenedioxydichlorosilane (I) and bis(o-phenylenedioxy)silane (III). The former compound exists both as a monomer-dimer mixture (I and II) and as the pure dimer (II). 2,2’-Biphenylenedioxy-bis(methoxy)silane (V) was also prepared and its facile conversion to bis(2,2’-biphenylenedioxy)silane (VI) was observed.

Original languageEnglish (US)
Pages (from-to)97-104
Number of pages8
JournalSynthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Volume2
Issue number2
DOIs
StatePublished - Jan 1 1972

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Silanes
silanes
Dimers
silicon tetrachloride
dimers
acetonitrile
monomers
Monomers

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

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abstract = "The reaction between silicon tetrachloride and catechol in acetonitrile at 0° results in the formation of o-phenylenedioxydichlorosilane (I) and bis(o-phenylenedioxy)silane (III). The former compound exists both as a monomer-dimer mixture (I and II) and as the pure dimer (II). 2,2’-Biphenylenedioxy-bis(methoxy)silane (V) was also prepared and its facile conversion to bis(2,2’-biphenylenedioxy)silane (VI) was observed.",
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Substituted 5-Phenyl-10, ll-DihydroDibenzo[b, f]Silepins and Reactions at the 10, II-Positions. / Allcock, Harry R.; Nugent, T. A.; Smeltz, L. A.

In: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, Vol. 2, No. 2, 01.01.1972, p. 97-104.

Research output: Contribution to journalArticle

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T1 - Substituted 5-Phenyl-10, ll-DihydroDibenzo[b, f]Silepins and Reactions at the 10, II-Positions

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