SUBSTITUTION REACTIONS ON HALOGENATED POLYETHYLENE.

Ian R. Harrison, Jacqueline S. Butler, James Patrick Runt

Research output: Contribution to journalConference article

Abstract

Neutron activation analysis, FTIR and thermal analysis show that bromine on the surface of PE single crystals can be replaced by toluene by means of Friedel-Crafts reaction. Infrared analysis of the substituted (FC) crystals also shows that the majority of addition occurs by 1,3 and 1,4 substitution to the aromatic ring. The presence of bulky groups on the surface (Br or FC) inhibits any reorganization annealing by the crystals.

Original languageEnglish (US)
Pages (from-to)176-179
Number of pages4
JournalOrganic coatings and plastics chemistry
Volume44
StatePublished - Jan 1 1981
EventPrepr of Pap Presented at the ACS Natl Meet, 181st - Atlanta, Ga, USA
Duration: Mar 29 1981Apr 3 1981

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Polyethylenes
Substitution reactions
Friedel-Crafts reaction
Crystals
Neutron activation analysis
Bromine
Thermoanalysis
Toluene
Single crystals
Annealing
Infrared radiation

All Science Journal Classification (ASJC) codes

  • Engineering(all)

Cite this

Harrison, I. R., Butler, J. S., & Runt, J. P. (1981). SUBSTITUTION REACTIONS ON HALOGENATED POLYETHYLENE. Organic coatings and plastics chemistry, 44, 176-179.
Harrison, Ian R. ; Butler, Jacqueline S. ; Runt, James Patrick. / SUBSTITUTION REACTIONS ON HALOGENATED POLYETHYLENE. In: Organic coatings and plastics chemistry. 1981 ; Vol. 44. pp. 176-179.
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Harrison, IR, Butler, JS & Runt, JP 1981, 'SUBSTITUTION REACTIONS ON HALOGENATED POLYETHYLENE.', Organic coatings and plastics chemistry, vol. 44, pp. 176-179.

SUBSTITUTION REACTIONS ON HALOGENATED POLYETHYLENE. / Harrison, Ian R.; Butler, Jacqueline S.; Runt, James Patrick.

In: Organic coatings and plastics chemistry, Vol. 44, 01.01.1981, p. 176-179.

Research output: Contribution to journalConference article

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AU - Runt, James Patrick

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