SuFEx-based strategies for the preparation of functional particles and cation exchange resins

Andrew J. Kassick, Li Chen, Marina Kovaliov, Robert T. Mathers, Jason Locklin, Saadyah Averick

Research output: Contribution to journalArticle

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Abstract

A predictable and reproducible number of sulfuric acid sites have been achieved for cation exchange resins by employing a mild SuFEx-based reagent system to effect the hydrolysis of fluorosulfonated polymer beads. The resultant poly(hydrogen sulfate) beads effectively demonstrate their utility as cation exchange resins in ion-capture experiments. Furthermore, their polyfluorosulfonated precursors have also proven to be suitable substrates for traditional SuFEx-type click reactions in both small molecule and protein immobilization applications.

Original languageEnglish (US)
Pages (from-to)3891-3894
Number of pages4
JournalChemical Communications
Volume55
Issue number27
DOIs
StatePublished - Jan 1 2019

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All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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