Sulfonated poly(ether ether ketone)/polybenzimidazole oligomer/epoxy resin composite membranes in situ polymerization for direct methanol fuel cell usages

Miaomiao Han, Gang Zhang, Mingyu Li, Shuang Wang, Zhongguo Liu, Hongtao Li, Yang Zhang, Dan Xu, Jing Wang, Jing Ni, Hui Na

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

A diamine-terminated polybenzimidazole oligomer (o-PBI) has been synthesized for introducing the benzimidazole groups (BI) into sulfonated poly(ether ether ketone) (SPEEK) membranes. SPEEK/o-PBI/4,4′-diglycidyl(3, 3′,5,5′-tetramethylbiphenyl) epoxy resin (TMBP) composite membranes in situ polymerization has been prepared for the purpose of improving the performance of SPEEK with high ion-exchange capacities (IEC) for the usage in the direct methanol fuel cells (DMFCs). The composite membranes with three-dimensional network structure are obtained through a cross-linking reaction between PBI oligomer and TMBP and the acid-base interaction between sulfonic acid groups and benzimidazole groups. Resulting membranes show a significantly increasing of all of the properties, such as high proton conductivity (0.14 S cm-1 at 80 °C), low methanol permeability (2.38 × 10-8 cm2 s-1), low water uptake (25.66% at 80 °C) and swelling ratio (4.11% at 80 °C), strong thermal and oxidative stability, and mechanical properties. Higher selectivity has been found for the composite membranes in comparison with SPEEK. Therefore, the SPEEK/o-PBI/TMBP composite membranes show a good potential in DMFCs usages.

Original languageEnglish (US)
Pages (from-to)9916-9923
Number of pages8
JournalJournal of Power Sources
Volume196
Issue number23
DOIs
StatePublished - Dec 1 2011

Fingerprint

polybenzimidazole
Epoxy Resins
Polyether ether ketones
Direct methanol fuel cells (DMFC)
Composite membranes
epoxy resins
oligomers
Oligomers
Epoxy resins
ketones
fuel cells
ethers
polymerization
methyl alcohol
Polymerization
membranes
composite materials
Membranes
Diamines
Proton conductivity

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Physical and Theoretical Chemistry
  • Electrical and Electronic Engineering

Cite this

Han, Miaomiao ; Zhang, Gang ; Li, Mingyu ; Wang, Shuang ; Liu, Zhongguo ; Li, Hongtao ; Zhang, Yang ; Xu, Dan ; Wang, Jing ; Ni, Jing ; Na, Hui. / Sulfonated poly(ether ether ketone)/polybenzimidazole oligomer/epoxy resin composite membranes in situ polymerization for direct methanol fuel cell usages. In: Journal of Power Sources. 2011 ; Vol. 196, No. 23. pp. 9916-9923.
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abstract = "A diamine-terminated polybenzimidazole oligomer (o-PBI) has been synthesized for introducing the benzimidazole groups (BI) into sulfonated poly(ether ether ketone) (SPEEK) membranes. SPEEK/o-PBI/4,4′-diglycidyl(3, 3′,5,5′-tetramethylbiphenyl) epoxy resin (TMBP) composite membranes in situ polymerization has been prepared for the purpose of improving the performance of SPEEK with high ion-exchange capacities (IEC) for the usage in the direct methanol fuel cells (DMFCs). The composite membranes with three-dimensional network structure are obtained through a cross-linking reaction between PBI oligomer and TMBP and the acid-base interaction between sulfonic acid groups and benzimidazole groups. Resulting membranes show a significantly increasing of all of the properties, such as high proton conductivity (0.14 S cm-1 at 80 °C), low methanol permeability (2.38 × 10-8 cm2 s-1), low water uptake (25.66{\%} at 80 °C) and swelling ratio (4.11{\%} at 80 °C), strong thermal and oxidative stability, and mechanical properties. Higher selectivity has been found for the composite membranes in comparison with SPEEK. Therefore, the SPEEK/o-PBI/TMBP composite membranes show a good potential in DMFCs usages.",
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Sulfonated poly(ether ether ketone)/polybenzimidazole oligomer/epoxy resin composite membranes in situ polymerization for direct methanol fuel cell usages. / Han, Miaomiao; Zhang, Gang; Li, Mingyu; Wang, Shuang; Liu, Zhongguo; Li, Hongtao; Zhang, Yang; Xu, Dan; Wang, Jing; Ni, Jing; Na, Hui.

In: Journal of Power Sources, Vol. 196, No. 23, 01.12.2011, p. 9916-9923.

Research output: Contribution to journalArticle

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T1 - Sulfonated poly(ether ether ketone)/polybenzimidazole oligomer/epoxy resin composite membranes in situ polymerization for direct methanol fuel cell usages

AU - Han, Miaomiao

AU - Zhang, Gang

AU - Li, Mingyu

AU - Wang, Shuang

AU - Liu, Zhongguo

AU - Li, Hongtao

AU - Zhang, Yang

AU - Xu, Dan

AU - Wang, Jing

AU - Ni, Jing

AU - Na, Hui

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