87Rb Dynamic-Angle Spinning NMR Spectroscopy of Inorganic Rubidium Salts

J. H. Baltisberger, S. L. Gann, A. Pines, E. W. Wooten, Karl Todd Mueller, K. T. Mueller

Research output: Contribution to journalArticle

45 Citations (Scopus)

Abstract

Five inorganic rubidium salts, RbCl, RbClO4, Rb2SO4, Rb2CrO4, and RbNO3, were examined using 87Rb NMR spectroscopy. Significant line narrowing occurs under dynamic-angle spinning (DAS) compared to magic-angle spinning (MAS) or variable-angle spinning (VAS). From DAS spectra acquired at various magnetic field strengths, isotropic chemical shifts and isotropic second-order quadrupolar shifts were obtained. By simulations of single-site line shapes obtained from MAS-detected DAS experiments, complete chemical shift and quadrupolar parameters were determined for each of the three crystallographically distinct rubidium sites in RbNO3.

Original languageEnglish (US)
Pages (from-to)7489-7493
Number of pages5
JournalJournal of the American Chemical Society
Volume114
Issue number19
DOIs
StatePublished - Sep 1 1992

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Rubidium
Nuclear magnetic resonance spectroscopy
Magic angle spinning
Magnetic Resonance Spectroscopy
Salts
Chemical shift
Magnetic Fields
Magnetic fields
Experiments

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Baltisberger, J. H., Gann, S. L., Pines, A., Wooten, E. W., Mueller, K. T., & Mueller, K. T. (1992). 87Rb Dynamic-Angle Spinning NMR Spectroscopy of Inorganic Rubidium Salts. Journal of the American Chemical Society, 114(19), 7489-7493. https://doi.org/10.1021/ja00045a023
Baltisberger, J. H. ; Gann, S. L. ; Pines, A. ; Wooten, E. W. ; Mueller, Karl Todd ; Mueller, K. T. / 87Rb Dynamic-Angle Spinning NMR Spectroscopy of Inorganic Rubidium Salts. In: Journal of the American Chemical Society. 1992 ; Vol. 114, No. 19. pp. 7489-7493.
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abstract = "Five inorganic rubidium salts, RbCl, RbClO4, Rb2SO4, Rb2CrO4, and RbNO3, were examined using 87Rb NMR spectroscopy. Significant line narrowing occurs under dynamic-angle spinning (DAS) compared to magic-angle spinning (MAS) or variable-angle spinning (VAS). From DAS spectra acquired at various magnetic field strengths, isotropic chemical shifts and isotropic second-order quadrupolar shifts were obtained. By simulations of single-site line shapes obtained from MAS-detected DAS experiments, complete chemical shift and quadrupolar parameters were determined for each of the three crystallographically distinct rubidium sites in RbNO3.",
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Baltisberger, JH, Gann, SL, Pines, A, Wooten, EW, Mueller, KT & Mueller, KT 1992, '87Rb Dynamic-Angle Spinning NMR Spectroscopy of Inorganic Rubidium Salts', Journal of the American Chemical Society, vol. 114, no. 19, pp. 7489-7493. https://doi.org/10.1021/ja00045a023

87Rb Dynamic-Angle Spinning NMR Spectroscopy of Inorganic Rubidium Salts. / Baltisberger, J. H.; Gann, S. L.; Pines, A.; Wooten, E. W.; Mueller, Karl Todd; Mueller, K. T.

In: Journal of the American Chemical Society, Vol. 114, No. 19, 01.09.1992, p. 7489-7493.

Research output: Contribution to journalArticle

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T1 - 87Rb Dynamic-Angle Spinning NMR Spectroscopy of Inorganic Rubidium Salts

AU - Baltisberger, J. H.

AU - Gann, S. L.

AU - Pines, A.

AU - Wooten, E. W.

AU - Mueller, Karl Todd

AU - Mueller, K. T.

PY - 1992/9/1

Y1 - 1992/9/1

N2 - Five inorganic rubidium salts, RbCl, RbClO4, Rb2SO4, Rb2CrO4, and RbNO3, were examined using 87Rb NMR spectroscopy. Significant line narrowing occurs under dynamic-angle spinning (DAS) compared to magic-angle spinning (MAS) or variable-angle spinning (VAS). From DAS spectra acquired at various magnetic field strengths, isotropic chemical shifts and isotropic second-order quadrupolar shifts were obtained. By simulations of single-site line shapes obtained from MAS-detected DAS experiments, complete chemical shift and quadrupolar parameters were determined for each of the three crystallographically distinct rubidium sites in RbNO3.

AB - Five inorganic rubidium salts, RbCl, RbClO4, Rb2SO4, Rb2CrO4, and RbNO3, were examined using 87Rb NMR spectroscopy. Significant line narrowing occurs under dynamic-angle spinning (DAS) compared to magic-angle spinning (MAS) or variable-angle spinning (VAS). From DAS spectra acquired at various magnetic field strengths, isotropic chemical shifts and isotropic second-order quadrupolar shifts were obtained. By simulations of single-site line shapes obtained from MAS-detected DAS experiments, complete chemical shift and quadrupolar parameters were determined for each of the three crystallographically distinct rubidium sites in RbNO3.

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Baltisberger JH, Gann SL, Pines A, Wooten EW, Mueller KT, Mueller KT. 87Rb Dynamic-Angle Spinning NMR Spectroscopy of Inorganic Rubidium Salts. Journal of the American Chemical Society. 1992 Sep 1;114(19):7489-7493. https://doi.org/10.1021/ja00045a023