Surface characterization of cross-linked elastomers by shear modulation force microscopy

Y. Zhang, S. Ge, M. H. Rafailovich, J. C. Sokolov, R. H. Colby

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

Brominated poly(isobutylene-co-4-methylstyrene) (BIMS) is a synthetic terpolymer which can be stoichiometrically cross-linked by N,N′dicinnamylidene-1,6-hexanediamine (DIAK). The degree of cross-links on bulk samples was determined by measuring the low frequency shear modulus with parallel plate method. The surface modulus of the same samples was measured using a new method, shear modulation force microscopy (SMFM). The moduli of the bulk sample and the surface were found to have the same scaling with the cross-link density, and good agreement with rubber elasticity theory was obtained in both cases. The SMFM was then used to monitor the cross-linking process, as a function of DIAK concentration and curing time, in thin films where standard theological methods cannot be applied. The results show that in all cases the cross-linking reaction at the surface reaches saturation in less than 10 min as compared to at least 1 h in the bulk samples.

Original languageEnglish (US)
Pages (from-to)3327-3332
Number of pages6
JournalPolymer
Volume44
Issue number11
DOIs
StatePublished - Apr 30 2003

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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