Synthesis and characterization of aminoorganosiloxane-bearing polyphosphazenes: New properties by the elimination of hydrogen bonding

Harry R. Allcock, Susan E. Kuharcik, Constance J. Nelson

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The synthesis of new hybrid polyphosphazene-siloxane polymers is described. These polymers contain a polyphosphazene backbone and [(N-methylamino)propyl]siloxane side groups, -N(Me)-(CH2)3SiMe2OSiMe3 or -N(Me)(CH2)3SiMe2OSiMe2OSiMe 3, in ratios of 1:1 and 1:3 with trifluoroethoxy, 2-(2-methoxyethoxy)ethoxy, or p-methylphenoxy cosubstituents. The synthetic method utilized allows the polymer properties to be tuned by variations in the cosubstituent ratios. The polymers were characterized by 31P, 13C, and 1H NMR, differential scanning calorimetry (DSC), gel permeation chromatography (GPC), and elemental analysis. The percent loading of siloxane-containing side groups and the nature of the cosubstituents were correlated to the glass transition temperatures. The glass transition temperatures ranged from -83 to -22°C. The longer, trisiloxane-containing units generated lower glass transition temperatures than did the analogous polymers with disiloxane-containing side groups. Several polymers were further characterized by dynamic mechanical analysis (DMA). In addition to glass transition temperatures, other transitions attributed to the siloxane side groups were detected at approximately -124°C.

Original languageEnglish (US)
Pages (from-to)3686-3693
Number of pages8
JournalMacromolecules
Volume29
Issue number11
DOIs
StatePublished - May 20 1996

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Bearings (structural)
Siloxanes
Hydrogen bonds
Polymers
Gel permeation chromatography
Dynamic mechanical analysis
Differential scanning calorimetry
Nuclear magnetic resonance
Glass transition temperature
Chemical analysis

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

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abstract = "The synthesis of new hybrid polyphosphazene-siloxane polymers is described. These polymers contain a polyphosphazene backbone and [(N-methylamino)propyl]siloxane side groups, -N(Me)-(CH2)3SiMe2OSiMe3 or -N(Me)(CH2)3SiMe2OSiMe2OSiMe 3, in ratios of 1:1 and 1:3 with trifluoroethoxy, 2-(2-methoxyethoxy)ethoxy, or p-methylphenoxy cosubstituents. The synthetic method utilized allows the polymer properties to be tuned by variations in the cosubstituent ratios. The polymers were characterized by 31P, 13C, and 1H NMR, differential scanning calorimetry (DSC), gel permeation chromatography (GPC), and elemental analysis. The percent loading of siloxane-containing side groups and the nature of the cosubstituents were correlated to the glass transition temperatures. The glass transition temperatures ranged from -83 to -22°C. The longer, trisiloxane-containing units generated lower glass transition temperatures than did the analogous polymers with disiloxane-containing side groups. Several polymers were further characterized by dynamic mechanical analysis (DMA). In addition to glass transition temperatures, other transitions attributed to the siloxane side groups were detected at approximately -124°C.",
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Synthesis and characterization of aminoorganosiloxane-bearing polyphosphazenes : New properties by the elimination of hydrogen bonding. / Allcock, Harry R.; Kuharcik, Susan E.; Nelson, Constance J.

In: Macromolecules, Vol. 29, No. 11, 20.05.1996, p. 3686-3693.

Research output: Contribution to journalArticle

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AB - The synthesis of new hybrid polyphosphazene-siloxane polymers is described. These polymers contain a polyphosphazene backbone and [(N-methylamino)propyl]siloxane side groups, -N(Me)-(CH2)3SiMe2OSiMe3 or -N(Me)(CH2)3SiMe2OSiMe2OSiMe 3, in ratios of 1:1 and 1:3 with trifluoroethoxy, 2-(2-methoxyethoxy)ethoxy, or p-methylphenoxy cosubstituents. The synthetic method utilized allows the polymer properties to be tuned by variations in the cosubstituent ratios. The polymers were characterized by 31P, 13C, and 1H NMR, differential scanning calorimetry (DSC), gel permeation chromatography (GPC), and elemental analysis. The percent loading of siloxane-containing side groups and the nature of the cosubstituents were correlated to the glass transition temperatures. The glass transition temperatures ranged from -83 to -22°C. The longer, trisiloxane-containing units generated lower glass transition temperatures than did the analogous polymers with disiloxane-containing side groups. Several polymers were further characterized by dynamic mechanical analysis (DMA). In addition to glass transition temperatures, other transitions attributed to the siloxane side groups were detected at approximately -124°C.

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