Synthesis and isolation of molybdenum atomic wires

Hiroyuki Muramatsu, Takuya Hayashi, Yoong Ahm Kim, Daisuke Shimamoto, Morinobu Endo, Mauricio Terrones, Mildred S. Dresselhaus

Research output: Contribution to journalArticle

49 Scopus citations

Abstract

One of the main challenges in nanoscience and nanotechnology consists in the production and isolation of metallic atomic-scale nanowires (Benzryadin, C. N.; Lau, A.; Tinkham, M. Q. Nature 2000, 404, 971-974; Zach, M. P.; Ng, K. H.; Penner, R. M. Science 2000, 290, 2120-2123; Nilius, N.; Wallis, T. M.; Ho, W. Science 2002, 297, 1853-1856.). Here we report a unique and controllable way of isolating individual atomic molybdenum (Mo) chains by their encapsulation inside double-walled carbon nanotubes, exhibiting inner diameters ranging from 0.6 to 0.8 nm. We have found that these individual atomic chains form spontaneously within the hollow core of tubes in the absence of any reducing agent. We believe that these atomic-scale nanowires could now be studied without suffering oxidation, so that their physical and chemical properties are elucidated.

Original languageEnglish (US)
Pages (from-to)237-240
Number of pages4
JournalNano letters
Volume8
Issue number1
DOIs
StatePublished - Jan 1 2008

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering

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    Muramatsu, H., Hayashi, T., Kim, Y. A., Shimamoto, D., Endo, M., Terrones, M., & Dresselhaus, M. S. (2008). Synthesis and isolation of molybdenum atomic wires. Nano letters, 8(1), 237-240. https://doi.org/10.1021/nl0725188