Synthesis and X-ray data of M(TiCr)P3O12, Cu(I)Ti2P3O12 and Cu(I)1+2xZr2-xCu(II)xP3O12-x

The synthesis, X-ray diffraction (XRD) analysis and the lattice parameter determination of NaZr₂P₃O₁₂ (NZP) materials are investigated. In one series, the M-site was occupied by a divalent metal, and the two A-sites by Ti and Cr atoms. In another series, the M-site was occupied by Cu(I) and the A-site by either Ti or a combination of Zr and Cu(II). All synthesized materials were pure phase with a clear NZP structure. The standard deviations were determined from 3 runs of the same composition Ba(TiCR)P₃O₁₂. The standard deviation was 0.0012 nm for the a parameter and 0.0088 nm for the c parameter.