Synthesis, characterization, and alignment of magnetic carbon nanotubes tethered with maghemite nanoparticles

Il Tae Kim, Grady A. Nunnery, Karl Jacob, Justin Schwartz, Xiaotao Liu, Rina Tannenbaum

Research output: Contribution to journalArticle

85 Scopus citations

Abstract

In this work we describe a novel, facile method for the decoration of multiwalled carbon nanotubes (MWNTs) with nearly monodisperse γ-Fe 2O3 magnetic (maghemite) nanoparticles and their alignment in a magnetic field. The tethering of the nanoparticles was achieved by the initial activation of the surface of the MWNTs with carboxylic acid groups, followed by the attachment of the γ--Fe2O3 nanoparticles via their synthesis using a modified sol-gel proess. Sodium dodecylbenzenesulfonate (NaDDBS) was introduced into the suspension as a surfactant in order to prevent the formation of an iron oxide 3D network. Various characterization methods were used to confirm the formation of well-defined maghemite nanoparticles and show that they were tethered to the walls of the MWNTs. The tethered γ-Fe2O3 nanoparticles imparted magnetic characteristics to the MWNTs and allowed their alignment in the direction of an externally applied magnetic field. This facile alignment of MWNTs could promote the enhancement of various properties, e.g., mechanical or electrical properties, of the resulting composites.

Original languageEnglish (US)
Pages (from-to)6944-6951
Number of pages8
JournalJournal of Physical Chemistry C
Volume114
Issue number15
DOIs
StatePublished - Apr 22 2010

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

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