Synthesis, characterization and molecular structure of the [(η6-C6Me6)Ru(μ-N3) (N3)]2 complex and its reactions with some monodentate ligands

P. Govindaswamy, Hemant P. Yennawar, Mohan Rao Kollipara

Research output: Contribution to journalShort survey

26 Citations (Scopus)

Abstract

The reaction of complex [(η6-C6Me6) Ru(μ-Cl)Cl]2 (1) with sodium azide yielded complexes of the composition [(η6-C6Me6) Ru(μ-N3)(N3)]2 (2) and [(η6-C6Me6)Ru(μ-N3) (Cl)]2 (3), depending upon the reaction conditions. Complex 3 with excess of sodium azide in ethanol yielded complex 2 . Complexes 2 and 3 undergo substitution reactions with monodentate ligands such as PPh3, PMe2Ph and AsPh3 to yield monomeric complexes. The structure of complex 2 was determined by X-ray crystallography. All these complexes were characterized by micro analytical data and by FT-IR and FT-NMR spectroscopy. Complex 2 crystallizes in the monoclinic space group P21n with a = 8.5370(11) Å, b = 16.192(2) Å, c = 10.4535(13) Å and β = 110.877(2)°.

Original languageEnglish (US)
Pages (from-to)3108-3112
Number of pages5
JournalJournal of Organometallic Chemistry
Volume689
Issue number19
DOIs
StatePublished - Sep 22 2004

Fingerprint

Sodium Azide
Molecular Structure
Molecular structure
sodium azides
molecular structure
Ligands
Sodium
ligands
X ray crystallography
X Ray Crystallography
synthesis
Nuclear magnetic resonance spectroscopy
Ethanol
Substitution reactions
Magnetic Resonance Spectroscopy
crystallography
ethyl alcohol
Chemical analysis
substitutes
nuclear magnetic resonance

All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

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title = "Synthesis, characterization and molecular structure of the [(η6-C6Me6)Ru(μ-N3) (N3)]2 complex and its reactions with some monodentate ligands",
abstract = "The reaction of complex [(η6-C6Me6) Ru(μ-Cl)Cl]2 (1) with sodium azide yielded complexes of the composition [(η6-C6Me6) Ru(μ-N3)(N3)]2 (2) and [(η6-C6Me6)Ru(μ-N3) (Cl)]2 (3), depending upon the reaction conditions. Complex 3 with excess of sodium azide in ethanol yielded complex 2 . Complexes 2 and 3 undergo substitution reactions with monodentate ligands such as PPh3, PMe2Ph and AsPh3 to yield monomeric complexes. The structure of complex 2 was determined by X-ray crystallography. All these complexes were characterized by micro analytical data and by FT-IR and FT-NMR spectroscopy. Complex 2 crystallizes in the monoclinic space group P21n with a = 8.5370(11) {\AA}, b = 16.192(2) {\AA}, c = 10.4535(13) {\AA} and β = 110.877(2)°.",
author = "P. Govindaswamy and Yennawar, {Hemant P.} and Kollipara, {Mohan Rao}",
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Synthesis, characterization and molecular structure of the [(η6-C6Me6)Ru(μ-N3) (N3)]2 complex and its reactions with some monodentate ligands. / Govindaswamy, P.; Yennawar, Hemant P.; Kollipara, Mohan Rao.

In: Journal of Organometallic Chemistry, Vol. 689, No. 19, 22.09.2004, p. 3108-3112.

Research output: Contribution to journalShort survey

TY - JOUR

T1 - Synthesis, characterization and molecular structure of the [(η6-C6Me6)Ru(μ-N3) (N3)]2 complex and its reactions with some monodentate ligands

AU - Govindaswamy, P.

AU - Yennawar, Hemant P.

AU - Kollipara, Mohan Rao

PY - 2004/9/22

Y1 - 2004/9/22

N2 - The reaction of complex [(η6-C6Me6) Ru(μ-Cl)Cl]2 (1) with sodium azide yielded complexes of the composition [(η6-C6Me6) Ru(μ-N3)(N3)]2 (2) and [(η6-C6Me6)Ru(μ-N3) (Cl)]2 (3), depending upon the reaction conditions. Complex 3 with excess of sodium azide in ethanol yielded complex 2 . Complexes 2 and 3 undergo substitution reactions with monodentate ligands such as PPh3, PMe2Ph and AsPh3 to yield monomeric complexes. The structure of complex 2 was determined by X-ray crystallography. All these complexes were characterized by micro analytical data and by FT-IR and FT-NMR spectroscopy. Complex 2 crystallizes in the monoclinic space group P21n with a = 8.5370(11) Å, b = 16.192(2) Å, c = 10.4535(13) Å and β = 110.877(2)°.

AB - The reaction of complex [(η6-C6Me6) Ru(μ-Cl)Cl]2 (1) with sodium azide yielded complexes of the composition [(η6-C6Me6) Ru(μ-N3)(N3)]2 (2) and [(η6-C6Me6)Ru(μ-N3) (Cl)]2 (3), depending upon the reaction conditions. Complex 3 with excess of sodium azide in ethanol yielded complex 2 . Complexes 2 and 3 undergo substitution reactions with monodentate ligands such as PPh3, PMe2Ph and AsPh3 to yield monomeric complexes. The structure of complex 2 was determined by X-ray crystallography. All these complexes were characterized by micro analytical data and by FT-IR and FT-NMR spectroscopy. Complex 2 crystallizes in the monoclinic space group P21n with a = 8.5370(11) Å, b = 16.192(2) Å, c = 10.4535(13) Å and β = 110.877(2)°.

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