Synthesis, characterization, and reactivity of new platinum(II) alkyl alkene complexes

Naomi Basickes, Alan C. Hutson, Ayusman Sen, Glen P.A. Yap, Arnold L. Rheingold

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

A new Pt(II) ethyl ethene complex, [Pt(μ-Cl)-(CH2CH3)(C2H4] 2, (1), was isolated from the reaction of ethene with K2PtCl4 in water, and the structure was confirmed by X-ray crystallography. The results of oxidation experiments involving 1 indicate that PtII-C2H5 and PtII-(CH2=CH2) species are viable intermediates in the conversion of ethane to ethanol and ethane-1,2-diol by the Shilov system.

Original languageEnglish (US)
Pages (from-to)4116-4118
Number of pages3
JournalOrganometallics
Volume15
Issue number20
DOIs
StatePublished - Oct 1 1996

Fingerprint

Ethane
Alkenes
Platinum
ethane
alkenes
platinum
reactivity
X ray crystallography
synthesis
crystallography
ethyl alcohol
Ethanol
Oxidation
oxidation
Water
water
x rays
Experiments
ethylene

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Cite this

Basickes, Naomi ; Hutson, Alan C. ; Sen, Ayusman ; Yap, Glen P.A. ; Rheingold, Arnold L. / Synthesis, characterization, and reactivity of new platinum(II) alkyl alkene complexes. In: Organometallics. 1996 ; Vol. 15, No. 20. pp. 4116-4118.
@article{ca5d886985ea4123ab9d4107f653902c,
title = "Synthesis, characterization, and reactivity of new platinum(II) alkyl alkene complexes",
abstract = "A new Pt(II) ethyl ethene complex, [Pt(μ-Cl)-(CH2CH3)(C2H4] 2, (1), was isolated from the reaction of ethene with K2PtCl4 in water, and the structure was confirmed by X-ray crystallography. The results of oxidation experiments involving 1 indicate that PtII-C2H5 and PtII-(CH2=CH2) species are viable intermediates in the conversion of ethane to ethanol and ethane-1,2-diol by the Shilov system.",
author = "Naomi Basickes and Hutson, {Alan C.} and Ayusman Sen and Yap, {Glen P.A.} and Rheingold, {Arnold L.}",
year = "1996",
month = "10",
day = "1",
doi = "10.1021/om960495u",
language = "English (US)",
volume = "15",
pages = "4116--4118",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "20",

}

Synthesis, characterization, and reactivity of new platinum(II) alkyl alkene complexes. / Basickes, Naomi; Hutson, Alan C.; Sen, Ayusman; Yap, Glen P.A.; Rheingold, Arnold L.

In: Organometallics, Vol. 15, No. 20, 01.10.1996, p. 4116-4118.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Synthesis, characterization, and reactivity of new platinum(II) alkyl alkene complexes

AU - Basickes, Naomi

AU - Hutson, Alan C.

AU - Sen, Ayusman

AU - Yap, Glen P.A.

AU - Rheingold, Arnold L.

PY - 1996/10/1

Y1 - 1996/10/1

N2 - A new Pt(II) ethyl ethene complex, [Pt(μ-Cl)-(CH2CH3)(C2H4] 2, (1), was isolated from the reaction of ethene with K2PtCl4 in water, and the structure was confirmed by X-ray crystallography. The results of oxidation experiments involving 1 indicate that PtII-C2H5 and PtII-(CH2=CH2) species are viable intermediates in the conversion of ethane to ethanol and ethane-1,2-diol by the Shilov system.

AB - A new Pt(II) ethyl ethene complex, [Pt(μ-Cl)-(CH2CH3)(C2H4] 2, (1), was isolated from the reaction of ethene with K2PtCl4 in water, and the structure was confirmed by X-ray crystallography. The results of oxidation experiments involving 1 indicate that PtII-C2H5 and PtII-(CH2=CH2) species are viable intermediates in the conversion of ethane to ethanol and ethane-1,2-diol by the Shilov system.

UR - http://www.scopus.com/inward/record.url?scp=0000072407&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0000072407&partnerID=8YFLogxK

U2 - 10.1021/om960495u

DO - 10.1021/om960495u

M3 - Article

AN - SCOPUS:0000072407

VL - 15

SP - 4116

EP - 4118

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 20

ER -