Synthesis, characterization, and redox behavior of six-coordinate (por)Ru(NO)Cl compounds (por = porphyrinato dianion)

Nan Xu; Jonghyuk Lee; Douglas R. Powell; George B. Richter-Addo

doi:10.1016/j.ica.2004.06.031

Synthesis, characterization, and redox behavior of six-coordinate (por)Ru(NO)Cl compounds (por = porphyrinato dianion)

Nan Xu, Jonghyuk Lee, Douglas R. Powell, George B. Richter-Addo

Division of Mathematics & Natural Sciences (Altoona)

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

A new high-yield preparative route to (por)Ru(NO)Cl compounds (por = porphyrinato dianion) from reactions of (por)Ru(NO)(alkoxide) precursors with boron trichloride is reported. These ruthenium nitrosyl chloride complexes are known to be useful precursors to (por)Ru(NO)-containing derivatives. The crystal structure of (OEP)Ru(NO)Cl (OEP = octaethylporphyrinato dianion) shows that the RuNO linkage is linear. The redox behavior of the (por)Ru(NO)Cl compounds has been determined by cyclic voltammetry. Analysis of the data reveals that the first oxidation of the (por)Ru(NO)Cl compounds is porphyrin-ring centered.

Original language	English (US)
Pages (from-to)	2855-2860
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	358
Issue number	10
DOIs	https://doi.org/10.1016/j.ica.2004.06.031
State	Published - Jun 15 2005

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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title = "Synthesis, characterization, and redox behavior of six-coordinate (por)Ru(NO)Cl compounds (por = porphyrinato dianion)",

abstract = "A new high-yield preparative route to (por)Ru(NO)Cl compounds (por = porphyrinato dianion) from reactions of (por)Ru(NO)(alkoxide) precursors with boron trichloride is reported. These ruthenium nitrosyl chloride complexes are known to be useful precursors to (por)Ru(NO)-containing derivatives. The crystal structure of (OEP)Ru(NO)Cl (OEP = octaethylporphyrinato dianion) shows that the RuNO linkage is linear. The redox behavior of the (por)Ru(NO)Cl compounds has been determined by cyclic voltammetry. Analysis of the data reveals that the first oxidation of the (por)Ru(NO)Cl compounds is porphyrin-ring centered.",

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T1 - Synthesis, characterization, and redox behavior of six-coordinate (por)Ru(NO)Cl compounds (por = porphyrinato dianion)

AU - Xu, Nan

AU - Lee, Jonghyuk

AU - Powell, Douglas R.

AU - Richter-Addo, George B.

PY - 2005/6/15

Y1 - 2005/6/15

N2 - A new high-yield preparative route to (por)Ru(NO)Cl compounds (por = porphyrinato dianion) from reactions of (por)Ru(NO)(alkoxide) precursors with boron trichloride is reported. These ruthenium nitrosyl chloride complexes are known to be useful precursors to (por)Ru(NO)-containing derivatives. The crystal structure of (OEP)Ru(NO)Cl (OEP = octaethylporphyrinato dianion) shows that the RuNO linkage is linear. The redox behavior of the (por)Ru(NO)Cl compounds has been determined by cyclic voltammetry. Analysis of the data reveals that the first oxidation of the (por)Ru(NO)Cl compounds is porphyrin-ring centered.

AB - A new high-yield preparative route to (por)Ru(NO)Cl compounds (por = porphyrinato dianion) from reactions of (por)Ru(NO)(alkoxide) precursors with boron trichloride is reported. These ruthenium nitrosyl chloride complexes are known to be useful precursors to (por)Ru(NO)-containing derivatives. The crystal structure of (OEP)Ru(NO)Cl (OEP = octaethylporphyrinato dianion) shows that the RuNO linkage is linear. The redox behavior of the (por)Ru(NO)Cl compounds has been determined by cyclic voltammetry. Analysis of the data reveals that the first oxidation of the (por)Ru(NO)Cl compounds is porphyrin-ring centered.

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JO - Inorganica Chimica Acta

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Synthesis, characterization, and redox behavior of six-coordinate (por)Ru(NO)Cl compounds (por = porphyrinato dianion)

Abstract

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