Synthesis of palladium complexes with an anionic P∼O chelate and their use in copolymerization of ethene with functionalized norbornene derivatives: Unusual functionality tolerance

Shengsheng Liu, Sachin Borkar, David Newsham, Hemant Yennawar, Ayusman Sen

Research output: Contribution to journalArticlepeer-review

90 Scopus citations

Abstract

A series of anionic P∼O ligands and corresponding palladium - allyl complexes have been synthesized. The latter, along with palladium species formed in situ, were employed for the copolymerization of ethene with functionalized norbornene derivatives. The formed copolymers had high norbornene content (>40 mol %). The systems are highly tolerant of reactive functionalities, and the copolymerizations can even be carried out in the presence of water.

Original languageEnglish (US)
Pages (from-to)210-216
Number of pages7
JournalOrganometallics
Volume26
Issue number1
DOIs
StatePublished - Jan 1 2007

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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