Synthesis of Photo-Cross-Linkable Chalcone-Bearing Polyphosphazenes

Harry R. Allcock, Charles G. Cameron

Research output: Contribution to journalArticle

62 Citations (Scopus)

Abstract

Cyclic and high-polymeric phosphazenes that bear 4-(l-oxo-l-phenyl-2-propen-3-yl)phenoxy (4-oxychalcone) side groups have been prepared to study their photochemical behavior. Small-molecule cyclic trimers of the general formula N3P3R5R′, where R = phenoxy, 2,2,2-trifluoroethoxy, chloro, and 4-oxychalcone and R′= 4-oxychalcone, were synthesized to model the cross-linking reactions at the highpolymer level. Single-substituent and cosubstituent polymeric phosphazenes [NPRR′]n, where R = phenoxy, 2,2,2-trifluoroethoxy, or 4-oxychalcone and R ′= 4-oxychalcone were also prepared. Their photolytic crosslinking was monitored by ultraviolet spectroscopy. The high-polymeric system is of interest for uses in photolithography, photocurable coatings, and the stabilization of nonlinear optical properties.

Original languageEnglish (US)
Pages (from-to)3131-3135
Number of pages5
JournalMacromolecules
Volume27
Issue number12
DOIs
StatePublished - Jun 1 1994

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Bearings (structural)
Chalcone
Photolithography
Ultraviolet spectroscopy
Crosslinking
Optical properties
Stabilization
Coatings
Molecules

All Science Journal Classification (ASJC) codes

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Allcock, Harry R. ; Cameron, Charles G. / Synthesis of Photo-Cross-Linkable Chalcone-Bearing Polyphosphazenes. In: Macromolecules. 1994 ; Vol. 27, No. 12. pp. 3131-3135.
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Synthesis of Photo-Cross-Linkable Chalcone-Bearing Polyphosphazenes. / Allcock, Harry R.; Cameron, Charles G.

In: Macromolecules, Vol. 27, No. 12, 01.06.1994, p. 3131-3135.

Research output: Contribution to journalArticle

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AB - Cyclic and high-polymeric phosphazenes that bear 4-(l-oxo-l-phenyl-2-propen-3-yl)phenoxy (4-oxychalcone) side groups have been prepared to study their photochemical behavior. Small-molecule cyclic trimers of the general formula N3P3R5R′, where R = phenoxy, 2,2,2-trifluoroethoxy, chloro, and 4-oxychalcone and R′= 4-oxychalcone, were synthesized to model the cross-linking reactions at the highpolymer level. Single-substituent and cosubstituent polymeric phosphazenes [NPRR′]n, where R = phenoxy, 2,2,2-trifluoroethoxy, or 4-oxychalcone and R ′= 4-oxychalcone were also prepared. Their photolytic crosslinking was monitored by ultraviolet spectroscopy. The high-polymeric system is of interest for uses in photolithography, photocurable coatings, and the stabilization of nonlinear optical properties.

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