Synthesis of Titanium Silicalite-1 with High Catalytic Performance for 1-Butene Epoxidation by Eliminating the Extraframework Ti

Ting Zhang, Yi Zuo, Min Liu, Chunshan Song, Xinwen Guo

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

Titanium silicalite-1 (TS-1) with little extraframework Ti was hydrothermally synthesized in a tetrapropylammonium hydroxide system using starch as the additive. The influences of the amount of starch added on the coordination states of titanium ions and the functional mechanism of starch were studied by various characterization means. The addition of starch slowed the crystallization rate of TS-1 so that the insertion rate of titanium to the framework matched well with that of silicon. Therefore, the generation of extraframework Ti, including the anatase TiO2 and octahedrally coordinated titanium, was eliminated. The catalytic performances of the TS-1 samples were evaluated in the epoxidation of 1-butene to produce butene oxide. The catalytic activity of TS-1 was improved significantly due to the increasing amount of framework Ti.

Original languageEnglish (US)
Pages (from-to)1034-1040
Number of pages7
JournalACS Omega
Volume1
Issue number5
DOIs
StatePublished - Nov 30 2016

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Chemical Engineering(all)

Fingerprint Dive into the research topics of 'Synthesis of Titanium Silicalite-1 with High Catalytic Performance for 1-Butene Epoxidation by Eliminating the Extraframework Ti'. Together they form a unique fingerprint.

  • Cite this